| Full text | |
| Author(s): |
Cicolani, Renato Salviato
;
de Oliveira-Filho, Antonio Gustavo Sampaio
;
de Lima Batista, Ana Paula
;
Demets, Gregoire Jean-Francois
Total Authors: 4
|
| Document type: | Journal article |
| Source: | JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY; v. N/A, p. 7-pg., 2023-02-13. |
| Abstract | |
We have prepared two new heterotrihalides inside methyl-bambus[6]uril, [Br2Cl](-)@MeBU[6] and [BrICl](-)@MeBU[6], both in solution and in the solid state. These heterotrihalides were used alongside with the first one our group has produced, [I2Cl](-)@MeBU[6], as halogenation agents in classical halogenation and iodine-based catalysts for organic reactions, with comparable yields to those obtained with pure dihalogens. (AU) | |
| FAPESP's process: | 17/18238-4 - Catalytic C-H activation reactions: computational study aiming atom efficiency in CO2 fixation |
| Grantee: | Ana Paula de Lima Batista |
| Support Opportunities: | Scholarships in Brazil - Post-Doctoral |
| FAPESP's process: | 16/12666-1 - Chemical and physical properties of bamabusurils, semi-cucurbiturils and calix4azulenes: three neglected cavitands |
| Grantee: | Grégoire Jean-François Demets |
| Support Opportunities: | Regular Research Grants |
| FAPESP's process: | 17/19595-5 - Properties and applications for the bambus6uril cavitand |
| Grantee: | Renato Salviato Cicolani |
| Support Opportunities: | Scholarships in Brazil - Doctorate |
| FAPESP's process: | 15/11714-0 - Reactivity, transformation, fixation, and spectroscopy of systems involving CO2 |
| Grantee: | Antonio Gustavo Sampaio de Oliveira Filho |
| Support Opportunities: | Regular Research Grants |