Study of the Biodegradation of PLA/PBAT Films after Biodegradation Tests in Soil and the Aqueous Medium

Author(s)

Barbosa Camargo Lamparelli, Rita de Cassia ; Montagna, Larissa Stieven ; Bernardo da Silva, Ana Paula ; do Amaral Montanheiro, Thais Larissa ; Lemes, Ana Paula

• Document type: Journal article
• Source: BIOINTERFACE RESEARCH IN APPLIED CHEMISTRY; v. 12, n. 1, p. 14-pg., 2022-02-15.

Abstract

The intense consumption of conventional plastics has been generating a series of problems for nature due to the accumulation of municipal solid waste because of its difficult degradation. Therefore, the use of biodegradable polymers becomes a good option to minimize these effects. Poly (lactide acid)/poly(butylene adipate-co-terephthalate) (PLA/PBAT) is a biodegradable blend that can be used mainly in applications that have a short shelf life. So, it is important to know the total biodegradation time of this blend. For this reason, PLA/PBAT films (1.5 x 1.5 x 0.15 cm) were produced by thermal compression molding to be subjected to biodegradation tests in soil and aqueous medium for 180 days. The films were characterized by visual analysis, weight loss measurements, differential scanning calorimetry (DSC), Fourier transforms infrared spectroscopy (FT-IR), contact angle, and scanning electron microscopy (SEM). DSC showed an increase of 0.7% in PLA crystallinity subjected to the aqueous medium, while FT-IR showed a reduction in the bands at 1710 cm-1 and 1100 cm-1, as a result of hydrolysis for both methodologies. The blend's hydrophilic character was increased after both degradation processes, presenting a reduction of 34.5% in the contact angle after biodegradation in soil. From the results, it was possible to conclude that PLA/PBAT films did not degrade completely, as expected, but showed signs that indicated the beginning of the degradation. The degradation was more effective in the aqueous medium. (AU)

• FAPESP's process: 17/24873-4 - PHBV and hydroxybutyrate functionalized CNT nanocomposite: kinetic study of crystallization and correlation with mechanical properties
• Grantee: Thaís Larissa do Amaral Montanheiro
• Support Opportunities: Scholarships in Brazil - Post-Doctoral
• FAPESP's process: 17/11386-8 - Study of the influence of accelerated photodegradation in the biodegradation in soil of Ecovio® films
• Grantee: Rita de Cássia Barbosa Camargo Lamparelli
• Support Opportunities: Scholarships in Brazil - Scientific Initiation