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Interface matters: Design of an efficient CaCu3Ti4O12-rGO photocatalyst

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Author(s):
Praxedes, F. M. ; Moreno, H. ; Simoes, A. Z. ; Teixeira, V. C. ; Nunes, R. S. ; Amoresi, R. A. C. ; Ramirez, M. A.
Total Authors: 7
Document type: Journal article
Source: Powder Technology; v. 404, p. 14-pg., 2022-05-16.
Abstract

Different strategies have been investigated to enhance optical properties of semiconductor oxides such as CaCu3Ti4O12, e.g., reduced graphene oxide. This research focuses on photoluminescent and photocatalytic properties of CaCu3Ti4O12-rGO composites. Micrometric CCTO and rGO particles were mixed to obtain compos-ites. (Micro)structure, photoluminescence, and photocatalytic properties were evaluated. CCTO-rGO composites displayed broad PL emission over the visible spectrum, useful for triggering photocatalytic applications (asymptotic to 380-750 nm). A shift in PL towards the violet region compared to pure CCTO along with an associated orange emission decrease may be ascribed to rGO activity as an electron donor/acceptor. Photocatalytic tests under UV light (325 nm) showed that 20%rGO (asymptotic to 25.88%) significantly improved rhodamine B removal/adsorption compared to pure CCTO (asymptotic to 9.64%). Results from this study show that CCTO-rGO composites may be a promising choice for future UV-visible light-driven photocatalytic devices with high adsorption/lower response time pro-moting sustainability in water purification methods and associated applications. (c) 2022 Elsevier B.V. All rights reserved. (AU)

FAPESP's process: 18/24465-6 - Study of the optical and electrical behavior of advanced ceramic nanocomposites of CaCu3Ti4O12/reduced graphene oxide
Grantee:Fernanda Malato Praxedes
Support Opportunities: Scholarships in Brazil - Master
FAPESP's process: 17/19143-7 - An experimental theoretical approach of conduction mechanisms and interface defects of heterostructure sensors based on P-N and N-N semiconductors from CeO2 matrices
Grantee:Rafael Aparecido Ciola Amoresi
Support Opportunities: Scholarships in Brazil - Post-Doctoral