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Probing modulated liquid crystal media with dielectric spectroscopy

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Author(s):
Rosseto, M. P. ; de Almeida, R. R. Ribeiro ; Lenzi, E. K. ; Evangelista, L. R. ; Zola, R. S.
Total Authors: 5
Document type: Journal article
Source: JOURNAL OF MOLECULAR LIQUIDS; v. 390, p. 8-pg., 2023-09-06.
Abstract

We use impedance spectroscopy to probe modulated liquid crystals. Chiral nematic samples are characterized and fabricated with a fixed amount of chiral dopant and Smectic-A in different geometries. The data are adjusted with a Poisson-Nernst-Planck (PNP)-like model. The low-frequency behavior of the conductivity is studied, and the behavior is associated with the ionic diffusivity across the cell. Diffusion across layered structures, contrary to what occurs when the structures are not layered, requires permeation of ions, which is reflected in the very low exponent characterizing diffusivity, indicating a cage-like behavior diffusion. Thus, this simple non-destructive technique can be used to probe the morphology of the material. (AU)

FAPESP's process: 14/50983-3 - INCT 2014: complex fluids
Grantee:Antonio Martins Figueiredo Neto
Support Opportunities: Research Projects - Thematic Grants