Background optimization of powder electron diffraction for implementation of the e-PDF technique and study of the local structure of iron oxide nanocrystals

Author(s)

Vardhan Mogili, Naga Vishnu ; Verissimo, Nathalia Carolina ; Abeykoon, A. M. Milinda ; Bozin, Emil S. ; Bettini, Jefferson ; Leite, Edson Roberto ; Souza Junior, Joao Batista

• Document type: Journal article
• Source: ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES; v. 79, p. 15-pg., 2023-09-01.

Abstract

The local structural characterization of iron oxide nanoparticles is explored using a total scattering analysis method known as pair distribution function (PDF) (also known as reduced density function) analysis. The PDF profiles are derived from background-corrected powder electron diffraction patterns (the e-PDF technique). Due to the strong Coulombic interaction between the electron beam and the sample, electron diffraction generally leads to multiple scattering, causing redistribution of intensities towards higher scattering angles and an increased background in the diffraction profile. In addition to this, the electron-specimen interaction gives rise to an undesirable inelastic scattering signal that contributes primarily to the background. The present work demonstrates the efficacy of a pre-treatment of the underlying complex background function, which is a combination of both incoherent multiple and inelastic scatterings that cannot be identical for different electron beam energies. Therefore, two different background subtraction approaches are proposed for the electron diffraction patterns acquired at 80 kV and 300 kV beam energies. From the least-square refinement (small-box modelling), both approaches are found to be very promising, leading to a successful implementation of the e-PDF technique to study the local structure of the considered nanomaterial. (AU)

• FAPESP's process: 18/13243-2 - Synthesis and characterization of nanostructured photocatalyst films of TiO2@±-Fe2O3 deposited by InkJet-Printing: application for decomposition of benzoadiazepine organic compounds
• Grantee: Nathália Carolina Verissimo
• Support Opportunities: Scholarships in Brazil - Post-Doctoral
• FAPESP's process: 21/03321-9 - Controlling the structure of semiconductor nanoparticles: surface, defects, and properties
• Grantee: João Batista Souza Junior
• Support Opportunities: Regular Research Grants
• FAPESP's process: 13/07296-2 - CDMF - Center for the Development of Functional Materials
• Grantee: Elson Longo da Silva
• Support Opportunities: Research Grants - Research, Innovation and Dissemination Centers - RIDC