Photooxidative Behavior of Polystyrene Nanocomposites Filled with Two-Dimensional Molybdenum Disulfide

Author(s)

Angulo, Aurianny Lima ; Rodriguez, Camila Laura ; Macedo Fechine, Guilhermino Jose

• Document type: Journal article
• Source: POLYMERS; v. 15, n. 9, p. 15-pg., 2023-04-28.

Abstract

This study aimed to investigate how an ultralow content of a molybdenum disulfide (MoS2) two-dimensional particle affects the photodegradation mechanism of polystyrene (PS). Here, an accelerated weathering study was presented on neat polystyrene and its nanocomposites produced with 0.001, 0.002, 0.003 and 0.005 wt% of molybdenum disulfide (MoS2) exposed for various irradiation intervals (up to 8 weeks). The polymer photo-transformations were monitored using size exclusion chromatography (SEC), infrared spectroscopy (FTIR), and UV-Vis spectroscopy. The FTIR and UV/Vis results indicate that the PS degradation mechanism was not altered by the presence of MoS2 particles; however, the degradation reactions were slowed down at higher MoS2 contents (>0.003%). The SEC results proved the stabilizer effect due to MoS2 particles, where M-n, M-w,and M-w/M-n values after 8 weeks were less modified when compared with the neat PS results. The MoS2 acted as a UV stabilizer, and these two-dimensional particles acted by deactivating the free radicals generated by the PS matrix, even considering the low amount of the filler (<0.005 wt%). (AU)

• FAPESP's process: 18/10910-8 - Photodegradation and photostabilization of polymer nanocomposites based on two-dimensional fillers
• Grantee: Guilhermino José Macêdo Fechine
• Support Opportunities: Regular Research Grants