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Magnetic polaron effect in Sr8-xEuxGa16Ge30 clathrates probed by electron spin resonance

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Author(s):
Rosa, P. F. S. ; Iwamoto, W. ; Holanda, L. M. ; Ribeiro, R. A. ; Pagliuso, P. G. ; Rettori, C. ; Avila, M. A.
Total Authors: 7
Document type: Journal article
Source: PHYSICAL REVIEW B; v. 87, n. 22, p. 5-pg., 2013-06-14.
Abstract

Single crystals of the type-I clathrate series Sr8-xEuxGa16Ge30 (x = 0.01-8) were grown by Ga flux and systematically studied by magnetic susceptibility, electrical resistivity, and electron spin resonance (ESR) measurements. Both magnetic transition temperatures (T-c and T*) were mapped as a function of x. We found that the Curie temperature (T-c) and the magnetic anomaly temperature (T*) decrease systematically as Eu is substituted by Sr until no ordering is observed above 2 K for x = 1.0. For samples where the rattling Einstein temperature of theta(E) approximate to 25-60 K lies above T-c, we have observed no features in the ESR data, suggesting that the Eu2+ 4f spin dynamics is weakly coupled to the rattling modes. As the temperature is lowered and the magnetic field is increased, the ESR linewidth (Delta H) behavior points to the formation of magnetic polarons. (AU)

FAPESP's process: 11/23650-5 - Investigation of band structure and Fermi surface in advanced complex materials studied by angle-resolved photoemission spectroscopy
Grantee:Cris Adriano
Support Opportunities: Scholarships abroad - Research Internship - Post-doctor
FAPESP's process: 06/60440-0 - Study of strongly correlated systems in extreme conditions
Grantee:Carlos Rettori
Support Opportunities: Research Projects - Thematic Grants
FAPESP's process: 09/09247-3 - Investigation of pressure induced ordered states in novel complex materials.
Grantee:Cris Adriano
Support Opportunities: Scholarships in Brazil - Post-Doctoral
FAPESP's process: 10/11949-3 - Electron spin resonance (ESR) in superconducting Fe-based pnictides
Grantee:Priscila Ferrari Silveira Rosa
Support Opportunities: Scholarships in Brazil - Doctorate
FAPESP's process: 11/01564-0 - Materials sciences on complex and advanced systems
Grantee:Pascoal Jose Giglio Pagliuso
Support Opportunities: Scholarships abroad - Research