Tracking of structural defects induced by Eu-doping in β-Ag₂MoO₄: their influences on electrical properties

Author(s):Show less -

Macchi, Carlos ; Petinardi, Guilherme Magalhaes ; Freire, Leonardo Almeida ; Castro, Miriam Susana ; Aldao, Celso Manuel ; Luiz, Thais Marcial ; Moura, Francisco ; Simoes, Alexandre Zirpoli ; Moreno, Henrique ; Longo, Elson ; Somoza, Alberto ; Assis, Marcelo ; Ponce, Miguel Adolfo

• Document type: Journal article
• Source: DALTON TRANSACTIONS; v. 53, n. 2, p. 10-pg., 2023-11-30.

Abstract

In this study, several methods were employed to investigate the electrical characteristics of beta-Ag2MoO4 systems, both Eu-doped and undoped, synthesized using the microwave-assisted hydrothermal method. The focus extended to understanding how synthesis time influences material defects, with doping fixed at 1%. A systematic shift in the silver vacancy (V-Ag) concentration was observed within the doped beta-Ag2MoO4 system. Specifically, this study demonstrated that the incorporation of Eu3+ into polycrystalline beta-Ag2MoO4 initially increases the V-Ag concentration. However, as the synthesis time progresses, the V-Ag concentration decreases, resulting in alterations in the resulting electrical properties, arising from the intricate interplay between the number of grain boundaries and carrier density. By combining information obtained from photoluminescence, positron annihilation lifetime spectroscopy, and impedance spectroscopy, a comprehensive conduction mechanism was formulated, shedding light on both doped and undoped beta-Ag2MoO4 systems. (AU)

• FAPESP's process: 13/07296-2 - CDMF - Center for the Development of Functional Materials
• Grantee: Elson Longo da Silva
• Support Opportunities: Research Grants - Research, Innovation and Dissemination Centers - RIDC