| Full text | |
| Author(s): |
Santos, Erick A.
;
Barros, Leticia M. S.
;
Peluso, Anna F. de F. V.
;
Galantini, Isabela
;
Goncalves, Josue M.
;
Maciel Filho, Rubens Maciel
;
Zanin, Hudson
Total Authors: 7
|
| Document type: | Journal article |
| Source: | CHEMICAL ENGINEERING JOURNAL; v. 493, p. 26-pg., 2024-06-01. |
| Abstract | |
Quasi-solid-state electrolytes (QSSEs) and electrolytes based on ionic liquids (ILs) hold promise for addressing the inherent instability and safety concerns associated with conventional organic electrolytes in lithium-sulfur batteries (LSBs). This review explores recent studies on electrolytes for LSBs, focusing on QSSEs and IL-based electrolytes. Prominent findings include the application of polymer-based QSSEs, which have shown superior ionic conductivity at room temperature. ILs have shown an effective suppression of polysulfide shuttle, such as 1Butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide ([Pyr14][TFSI]), contributing to extending the lifespan of LSBs. Furthermore, imidazolium-based cations in ILs used in QSSE and solid-state electrolytes (SSE) have demonstrated excellent electrode compatibility, reduced interfacial resistance, and prolonged cyclability. This review presents a concise analysis of the most outstanding electrolytes reported from 2013 to 2023. Finally, the prospects in designing QSSEs and IL-containing electrolytes guide the development of new and improved LSBs, ushering in potential breakthroughs in future energy storage technologies. (AU) | |
| FAPESP's process: | 21/09387-1 - In-situ FTIR and Raman spectroscopy of lithium-ion batteries and lithium-sulfur batteries |
| Grantee: | Murilo Machado Amaral |
| Support Opportunities: | Scholarships in Brazil - Doctorate |
| FAPESP's process: | 17/11986-5 - Generation and storage of New Energy: bringing technological development for the country |
| Grantee: | Ana Flávia Nogueira |
| Support Opportunities: | Research Grants - Research Centers in Engineering Program |
| FAPESP's process: | 22/02222-0 - Development of prototype pouch cells of lithium-sulfur (Li-S) batteries in solid-liquid state with high stability and advanced scale of technological maturity |
| Grantee: | Érick Alves Santos |
| Support Opportunities: | Scholarships in Brazil - Doctorate |
| FAPESP's process: | 23/08594-9 - Hydrogen production via ammonia reforming over ni-based catalysts in a microchannel reactor |
| Grantee: | Letícia Maria Sampaio Barros |
| Support Opportunities: | Scholarships in Brazil - Doctorate |