Microstructure and mechanical properties of an experimental lithium disilicate dental glass-ceramic

Author(s)

Vallerini, Bruna de F. ; Silva, Lais D. ; Villas-Boas, Mariana de O. C. ; Peitl, Oscar ; Zanotto, Edgar D. ; Pinelli, Ligia A. P.

• Document type: Journal article
• Source: CERAMICS INTERNATIONAL; v. 50, n. 1, p. 9-pg., 2023-12-05.

Abstract

After testing over 50 experimental lithium disilicate (LS2)-based glass-ceramic (GC) compositions and evaluating their glass-forming ability and the effect of various heat treatments on their crystallized fraction, crystal size, and morphology, a particularly promising formulation was selected for the optimization of the mechanical properties of materials. The specimens were divided into groups submitted to a nucleation heat treatment at different times and temperatures, i.e., T1 (500 degrees C/90 '), T2 (500 degrees C/180 '), T3 (500 degrees C/360 ') and T4 (480 degrees C/360 '), followed by a crystal growth treatment to induce the lithium metasilicate (700 degrees C) and LS2 (840 degrees C) phases. However, a third (minor) phase, lithium phosphate, also precipitated. IPS e.max CAD was used as the control group (C, 500 degrees C/360 '). The elastic modulus (E) was measured by the impulse excitation technique (ASTM E 1876-15), while the Vickers hardness (HV) and biaxial flexural strength (BFS) were determined by indentation and the piston-on-three balls test (ISO 6872), respectively. The E and HV results were analyzed by ANOVA one-way with Games-Howell post-hoc test, whereas the BFS data were investigated by Kruskal-Wallis with Dunn's post-hoc test (alpha = 0.05). The E of all GCs were within the expected range for commercial LS2 glass-ceramics. The T2 and T4 GCs exhibited the best properties when compared to the C group, and despite their relatively small crystallized fraction (similar to 57 %), they showed a hardness of 5.8 +/- 0.2 GPa, a value that is adequate and statistically equal to that of the control group. The same groups reached BFS values of 359 +/- 89 MPa and 493 +/- 147 MPa, respectively, which are also statistically equal to that of the C group (338 +/- 61 MPa). The mechanical properties of the material studied was successfully optimized through variations in the nucleation temperature and time, reaching values comparable to (but not better than) commercial dental glass-ceramics. (AU)

• FAPESP's process: 18/16295-3 - Effect of different crystaline fractions on the biaxial flexural strength of a CAD-type lithium disilicate glass ceramic
• Grantee: Artur Toshiharu Hirai Olivi
• Support Opportunities: Scholarships in Brazil - Scientific Initiation
• FAPESP's process: 13/07793-6 - CEPIV - Center for Teaching, Research and Innovation in Glass
• Grantee: Edgar Dutra Zanotto
• Support Opportunities: Research Grants - Research, Innovation and Dissemination Centers - RIDC