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Use of Kramers-Kronig Transform and VogelFulcher-Tammann Equation to Probe the Molecular Dynamics of Polyamide 10.10 Nanocomposites

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Author(s):
Pinto, G. M. ; Helal, E. ; Ribeiro, H. ; David, E. ; Fechine, G. J. M. ; Demarquette, N. R.
Total Authors: 6
Document type: Journal article
Source: 2023 IEEE CONFERENCE ON ELECTRICAL INSULATION AND DIELECTRIC PHENOMENA, CEIDP; v. N/A, p. 4-pg., 2023-01-01.
Abstract

A fundamental knowledge of polymer- nanoparticle interactions, and their impact on polymer dynamics, is essential for successfully achieving the desired characteristics of polymer nanocomposites. Within that scope, broadband dielectric spectroscopy (BDS) was used as a tool to investigate the effect of different 2D materials, i.e., graphene oxide (GO), hexagonal-boron nitride (h-BN), and molybdenum disulfide (MoS2) on the molecular dynamics of polyamide 10.10 (PA 1010) nanocomposites at extremely low contents. It was verified that the 2D materials increase the activation energy (Ea) of the a process in PA 1010, which indicates that the molecular dynamics are restricted by the two-dimensional structure of such particles. This is further evidenced by changes in the shape of the dielectric loss curve during interfacial polarization, which was enhanced for the nanocomposites. (AU)

FAPESP's process: 21/07858-7 - Unconventional characterizations of multifunctional hybrid polymadie 1010/2D nanomaterials based composites
Grantee:Gabriel Matheus Pinto
Support Opportunities: Scholarships abroad - Research Internship - Doctorate
FAPESP's process: 20/11496-0 - Polyamide 1010 and 2D nanomaterials based hybrid multifunctional nanocomposites
Grantee:Gabriel Matheus Pinto
Support Opportunities: Scholarships in Brazil - Doctorate