Study of the behaviour of cations in leaching of NCA lithium-ion batteries by electrodialysis

Author(s)

Lima, Anastassia Mariah Nunes de Oliveira ; Espinosa, Denise Crocce Romano ; Gobo, Luciana Assis ; Kumoto, Elio Augusto ; Botelho Junior, Amilton Barbosa ; Tenorio, Jorge Alberto Soares

• Document type: Journal article
• Source: ENVIRONMENTAL TECHNOLOGY; v. N/A, p. 12-pg., 2025-01-28.

Abstract

End-of-life lithium-ion batteries (LIBs) present an opportunity to generate a circular economy through recycling. One of the techniques that can contribute to the purification of leached batteries is electrodialysis. In this work, we present a study of current variation in relation to monovalent (Li), divalent (Ni and Co) and trivalent (Al) cations from the synthetic solution of an NCA-type lithium-ion battery leachate, using electrodialysis membranes (HDX-100 and HDX-200) at three different current densities (12.5, 18.75 and 25.0 mA/cm2) at room temperature (25 degrees C). After the experiments carried out, it was shown that the concentration of metals in solution influences the separation of equal charges, where increasing the current has no influence on the separation of the metals studied, but that the application of cycles with the cation concentrate generated can lead to the separation of Ni without the addition of any chemical reagent. These results presents more expressive due to the high concentration of Ni (26.1 g/L) compared to the other elements, which becomes an advantage in the application of electrodialysis cycles. (AU)

• FAPESP's process: 19/11866-5 - Development of innovative processes for the recovery of critical metals
• Grantee: Denise Crocce Romano Espinosa
• Support Opportunities: Research Projects - Thematic Grants
• FAPESP's process: 23/01032-5 - Separation of critical metals through supported liquid membrane: evaluation of synergistic interaction between organophosphorus and membranes
• Grantee: Amilton Barbosa Botelho Junior
• Support Opportunities: Scholarships abroad - Research Internship - Post-doctor
• FAPESP's process: 20/00493-0 - Sustainable mining: recovery of critical raw materials from batteries using environmentally friendly technologies
• Grantee: Jorge Alberto Soares Tenório
• Support Opportunities: Regular Research Grants
• FAPESP's process: 21/14842-0 - Elucidation of the organometallic complexation mechanism between organic extractants and rare earth elements
• Grantee: Amilton Barbosa Botelho Junior
• Support Opportunities: Scholarships in Brazil - Post-Doctoral