Hydrotalcite Supported on Polycaprolactone:Poly(methyl methacrylate) Fiber Membranes for Chlorogenic Acid Removal

Author(s)

Nascimento, Andressa Cristina de Almeida ; Malafatti, Joao Otavio Donizette ; Sierra e Silva, Maria Luiza Lopes ; Moreira, Ailton Jose ; Thomazi, Adriana Coatrini ; Quaranta, Simone ; Paris, Elaine Cristina

• Document type: Journal article
• Source: WATER; v. 17, n. 7, p. 20-pg., 2025-03-22.

Abstract

Polyphenols are organic molecules extracted from various fruits, such as coffee and citrus, that possess biological activity and antioxidant properties. However, the presence of polyphenols in the environment is hazardous to water quality and living health. Among a variety of water remediation methods, adsorption remains a staple in the field. Therefore, this work aims to develop porous polycaprolactone: poly(methyl methacrylate) (PCL:PMMA) membranes as a support for hydrotalcite immobilization for the removal of chlorogenic acid polyphenol (CGA) from aqueous solutions. Due to the hydrophilic nature of hydrotalcite, the adsorbent was functionalized with hexadecyltrimethylammonium bromide (CTAB) to increase its affinity for CGA, resulting in a removal efficiency of approximately 96%. Composite fiber membranes were prepared by solution-blowing spinning with specific amounts of hydrotalcite added (i.e., 1 to 60 wt%). A 3:1 PCL:PMMA blend resulted in superior mechanical traction (0.8 MPa) and stress deformation (70%) compared to pure PCL (0.7 MPa and 37%) and PMMA (0.1 MPa and 5%) fibers. PCL:PMMA membranes with 60% LDH-CTAB exhibited CGA removal rates equal to 55% in the first cycle while maintaining the capacity to remove 30% of the polyphenol after five consecutive reuses. Removal rates up to 90% could also be achieved with an appropriate adsorbent dose (2 g L-1). Adsorption was found to follow pseudo-second-order kinetics and was adequately described by the Langmuir model, saturating LDH-CTAB active sites in four hours. PCL:PMMA:LDH-CTAB composites can be considered a potential alternative to support adsorbents for water remediation. (AU)

• FAPESP's process: 22/06219-3 - Developing and disseminating new technologies for environmental remediation of emerging contaminants
• Grantee: Ailton Jose Moreira
• Support Opportunities: Generation Project Research Grant
• FAPESP's process: 23/03632-0 - Development of sensor arrays based on zeolite nanostructures functionalized with porphyrins for polyphenol detection
• Grantee: João Otávio Donizette Malafatti
• Support Opportunities: Scholarships abroad - Research Internship - Post-doctor
• FAPESP's process: 23/07525-3 - Developing and disseminating new technologies for environmental remediation of emerging contaminants
• Grantee: Ailton Jose Moreira
• Support Opportunities: Scholarships in Brazil - Generation Project
• FAPESP's process: 21/14992-1 - Obtainment of nanocomposite membranes consisting of PCL/PMMA/zeolite for application as a chemical sensor in the detection of polyphenol residues from the coffee industry
• Grantee: João Otávio Donizette Malafatti
• Support Opportunities: Scholarships in Brazil - Post-Doctoral