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(Reference retrieved automatically from Web of Science through information on FAPESP grant and its corresponding number as mentioned in the publication by the authors.)

CHEMICAL DEGRADATION OF ESFENVALERATE AND HPLC-UV-PAD DETECTION OF INTERMEDIATES AND BY-PRODUCTS

Full text
Author(s):
Colombo, Renata [1] ; Yariwake, Janete Harumi [1] ; de Vasconcelos Lanza, Marcos Roberto [1]
Total Authors: 3
Affiliation:
[1] Univ Sao Paulo, Inst Quim Sao Carlos, BR-13560970 Sao Carlos, SP - Brazil
Total Affiliations: 1
Document type: Journal article
Source: Journal of Liquid Chromatography & Related Technologies; v. 35, n. 8, p. 1081-1090, 2012.
Web of Science Citations: 2
Abstract

The impact of pyretroids, their by-products and degradation products on humans and the environment is recognized as a serious problem. Despite several studies regarding esfenvalerate toxicity and its detection in water and sediments, there is still a lack of information about its degradation intermediates and by-products in water. In this work, an HPLC method was developed to follow up the degradation of esfenvalerate and to detect the intermediates and by-products formed during the chemical degradation process. The chemical degradation was performed using an esfenvalerate suspension and different concentrations of hydrogen peroxide, temperatures, and pH. The reaction was monitored for 24 hr, and during the kinetic experiments, samples were collected at several reaction times and analyzed by HPLC-UV-PAD. In the degradation process, eleven different compounds (intermediate and by-products) were detected, among them the metabolites 3-phenoxybenzoic acid and 3-phenoxybenzaldehyde. HPLC-UV-PAD proved to be a valuable analytical technique for the rapid and reliable separation and determination of esfenvalerate, its degradation intermediates, and by-products. (AU)

FAPESP's process: 10/05711-4 - Applications of SBSE (SBSE/LC, SBSE/GC) for the chemical-analytical study of Passiflora alata and P. edulis (maracujá) fruit, with emphasis to potentially toxic natural products
Grantee:Janete Harumi Yariwake
Support type: Regular Research Grants
FAPESP's process: 07/08314-3 - Organophosphrous pesticides degradation (chlorpyrifos, methyl-parathion and profenofos) via electrochemical and advanced oxidation processes
Grantee:Marcos Roberto de Vasconcelos Lanza
Support type: Regular Research Grants
FAPESP's process: 07/04759-0 - Gas diffusion electrodes modified by organometallic compounds for hydrogen peroxide production
Grantee:Marcos Roberto de Vasconcelos Lanza
Support type: Regular Research Grants