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CO2 photoconversion in products with value-added: experimental and theoric studies

Grant number: 18/09723-9
Support type:Regular Research Grants
Duration: November 01, 2018 - October 31, 2020
Field of knowledge:Engineering - Chemical Engineering
Principal Investigator:Francisco Guilherme Esteves Nogueira
Grantee:Francisco Guilherme Esteves Nogueira
Home Institution: Centro de Ciências Exatas e de Tecnologia (CCET). Universidade Federal de São Carlos (UFSCAR). São Carlos , SP, Brazil
Assoc. researchers:André Esteves Nogueira ; Cauê Ribeiro de Oliveira ; Luis Augusto Martins Ruotolo ; Teodorico de Castro Ramalho

Abstract

In recent decades with the population growth and the increase in industrial activity, the energy demand has increased significantly. However, the major source of energy consumed is fossil fuels. The burning of fossil fuels increases the quantity of greenhouse gases in atmosphere that can lead to global warming. Among these gases, carbon dioxide (CO2) is one of the main causes of the greenhouse effect. Thus, the development of new technologies for the production of clean energy through sustainable routes is fundamental. Among these technologies the process of photoconversion of CO2 (artificial photosynthesis) into value-added products, such as hydrocarbons, alcohols, organic acids and others, can be highlighted. In this context, this project aims to develop niobium oxide-based semiconductors (Nb2O5) modified with iron (Fe) and/or zinc (Zn) for the photoreduction of CO2 in products with added value. In addition, a detailed study of the structure and morphology of the materials was carried out, as well as theoretical computational studies, which support the investigation of photocatalytic properties. For the structural and morphological study, materials were characterized by X-ray absorption spectroscopy (XAS), X-ray diffractometry (XRD), Raman scattering spectroscopy, diffuse reflection spectroscopy (DRS), thermal analysis, scanning electron microscopy (SEM), high resolution transmission electron microscopy (HR-TEM) and nitrogen physisorption. Theoretical studies were carried out aiming at a greater understanding of the electronic properties as well as the mechanisms involved in the CO2 of photoconversion process. (AU)

Scientific publications
(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)
OLIVEIRA, JESSICA A.; REIS, MARIANA O.; PIRES, MAIRA S.; RUOTOLO, LUIS A. M.; RAMALHO, TEODORICO C.; OLIVEIRA, CAUE R.; LACERDA, LIVIA C. T.; NOGUEIRA, FRANCISCO G. E. Zn-doped Nb2O5 photocatalysts driven by visible-light: An experimental and theoretical study. Materials Chemistry and Physics, v. 228, p. 160-167, APR 15 2019. Web of Science Citations: 3.

Please report errors in scientific publications list by writing to: cdi@fapesp.br.