Red-Infrared active photonic materials for energy conversion and storage

• Grant number: 18/05280-5
• Support Opportunities: Regular Research Grants
• Start date: November 01, 2018
• End date: October 31, 2020
• Field of knowledge: Physical Sciences and Mathematics - Chemistry - Inorganic Chemistry
• Principal Investigator: Lucas Carvalho Veloso Rodrigues
• Grantee: Lucas Carvalho Veloso Rodrigues
• Host Institution: Instituto de Química (IQ). Universidade de São Paulo (USP). São Paulo , SP, Brazil
• City of the host institution: São Paulo
• Associated researchers: Andre Luiz Veiga Gimenes ; Flavia Vischi Winck ; Raphael Bertrand Heideier ; Verônica de Carvalho Teixeira

Abstract

There is great interest in the red-near infrared region of the spectrum due to its importance on energy photogeneration and bioimaging. This proposal describes the synthesis and application of luminescent materials in solar converters and bioimaging, particularly those with special luminescence properties as up- and down-conversion as well persistent luminescence. This project also approaches the new phenomenon of persistent up-conversion luminescence with important application in bioimaging. The persistent luminescence materials, which possess energy storage properties, will be applied to enhance the biomass production by microalgae. The up-conversion materials will be used to absorb near infrared radiation converting it to visible, reducing the transparency losses of solar converters. The down-conversion materials will reduce the thermalization losses by absorbing one high energy photon producing two lower energy photons, close to Silicon band gap energy. The application of these materials seeks the enhancement of solar energy usage. Finally, all the mechanisms from the emission and energy transfer processes will be clarified in order to improve the design of new materials. (AU)

Scientific publications

(10)

(The scientific publications listed on this page originate from the Web of Science or SciELO databases. Their authors have cited FAPESP grant or fellowship project numbers awarded to Principal Investigators or Fellowship Recipients, whether or not they are among the authors. This information is collected automatically and retrieved directly from those bibliometric databases.)

VENDRUSCOLO, VICTOR; GIORDANO, LUIDGI; LEOPOLDO CONSTANTINO, VERA REGINA; VELOSO RODRIGUES, LUCAS CARVALHO. Yb3+/Er(3+)co-doped Dion-Jacobson niobium layered perovskites as NIR-to-green upconversion materials. NEW JOURNAL OF CHEMISTRY, v. 44, n. 24, p. 10165-10171, JUN 28 2020. (18/05280-5, 14/50869-6)

HILARIO, ELOISA G.; RODRIGUES, LUCAS C., V; CAIUT, JOSE MAURICIO A.. Spectroscopic study of the 4f (n-1)5d transitions of LaPO4 doped with Pr3+ or co-doped with Pr3+ and Gd3+ in the vacuum ultra violet region. Nanotechnology, v. 33, n. 30, p. 10-pg., 2022-07-23. (18/05280-5, 16/11670-5)

FRITZEN, DOUGLAS L.; GIORDANO, LUIDGI; RODRIGUES, LUCAS C. V.; MONTEIRO, JORGE H. S. K.. Opportunities for Persistent Luminescent Nanoparticles in Luminescence Imaging of Biological Systems and Photodynamic Therapy. NANOMATERIALS, v. 10, n. 10, OCT 2020. (18/26282-6, 18/05280-5)

VENDRUSCOLO, VICTOR; GIORDANO, LUIDGI; LEOPOLDO CONSTANTINO, VERA REGINA; VELOSO RODRIGUES, LUCAS CARVALHO. Yb³⁺/Er³⁺co-doped Dion-Jacobson niobium layered perovskites as NIR-to-green upconversion materials. NEW JOURNAL OF CHEMISTRY, v. 44, n. 24, p. 7-pg., 2020-06-28. (18/05280-5, 14/50869-6)

ALMEIDA DOS SANTOS, DANILO ORMENI; GIORDANO, LUIDGI; STOCK GREIN BARBARA, MIGUEL AGUIRRE; PORTES, MARCELO CECCONI; SANTOS PEDROSO, CASSIO CARDOSO; TEIXEIRA, VERONICA CARVALHO; LASTUSAARI, MIKA; VELOSO RODRIGUES, LUCAS CARVALHO. Abnormal co-doping effect on the red persistent luminescence SrS:Eu2+,RE3+ materials. DALTON TRANSACTIONS, v. 49, n. 45, p. 16386-16393, DEC 7 2020. (17/09774-0, 13/07937-8, 18/05280-5)

GIORDANO, LUIDGI; CAI, GUANYU; SEGUIN, JOHANNE; LIU, JIANHUA; RICHARD, CYRILLE; RODRIGUES, LUCAS CARVALHO VELOSO; VIANA, BRUNO. Persistent Luminescence Induced by Upconversion: An Alternative Approach for Rechargeable Bio-Emitters. ADVANCED OPTICAL MATERIALS, v. N/A, p. 9-pg., 2023-01-18. (18/05280-5)

MERIZIO, L. G.; BONTURIM, E.; ICHIKAWA, R. U.; SILVA, I. G. N.; TEIXEIRA, V. C.; RODRIGUES, L. C. V.; BRITO, H. F.. Toward an energy-efficient synthesis method to improve persistent luminescence of Sr2MgSi2O7:Eu2+,Dy3+ materials. MATERIALIA, v. 20, DEC 2021. (10/19278-0, 18/05280-5, 19/21770-5)

GIORDANO, LUIDGI; NUNES, MATHEUS F.; TEIXEIRA, VERONICA C.; RODRIGUES, LUCAS C. V.. Green Synthesis of Upconverting NaYF4 and NaGdF4 Materials and Energy Levels Determination. Journal of the Brazilian Chemical Society, v. 32, n. 8, p. 1552-1558, AUG 2021. (18/05280-5)

VUORI, SAMI; COLINET, PAULINE; NORRBO, ISABELLA; STEININGER, RALPH; SAARINEN, TIMO; PALONEN, HEIKKI; PATURI, PETRIINA; RODRIGUES, V, LUCAS C.; GOTTLICHER, JORG; LE BAHERS, TANGUI; et al. etection of X-Ray Doses with Color-Changing Hackmanites: Mechanism and Applicatio. ADVANCED OPTICAL MATERIALS, v. 9, n. 20, JUL 2021. (18/05280-5)

FRITZEN, DOUGLAS L.; DE MATTOS, ELAINE A.; PETRI, DENISE F. S.; TEIXEIRA, VERONICA C.; BONTURIM, EVERTON; RODRIGUES, LUCAS C., V. Flexible translucent persistent luminescent films based on Sr2MgSi2O7:Eu2+,Dy3+ cellulose ether composites. DALTON TRANSACTIONS, v. 51, n. 23, p. 6-pg., 2022-05-25. (18/05280-5, 18/26282-6)