Multifunctional 3D photocatalytic systems for environmentally friendly sustainable technologies

• Grant number: 19/13471-8
• Support Opportunities: Regular Research Grants
• Start date: October 01, 2020
• End date: September 30, 2023
• Field of knowledge: Engineering - Materials and Metallurgical Engineering
• Agreement: M-ERA.NET
• Principal Investigator: Maraisa Gonçalves
• Grantee: Maraisa Gonçalves
• Principal researcher abroad: Joaquin Silvestre Albero
• Institution abroad: Universidad de Alicante (UA) , Spain
• Principal researcher abroad: Luminita Andronic
• Institution abroad: Transilvania University of Brasov (UTBv) , Romania
• Host Institution: Instituto de Ciência e Tecnologia (ICT). Universidade Federal de São Paulo (UNIFESP). Campus São José dos Campos. São José dos Campos , SP, Brazil
• City of the host institution: São José dos Campos
• Associated researchers: Elias de Barros Santos ; Mirabel Cerqueira Rezende ; Nirton Cristi Silva Vieira ; Raquel Aparecida Domingues
• Associated scholarship(s): 22/00087-8 - Synthesis of TiO2 nanoparticles for the preparation of hybrid structures with carbonaceous materials, BP.TT; 21/02348-0 - Synthesis and characterization of graphene derivatives for multifunctional applications, BP.TT; 21/02354-0 - Preparation and characterization of activated carbon for application as support for photocatalysts, BP.TT; 21/02350-5 - Photodegradation kinetics of wastewater pollutants: a photophysical study, BP.TT; 21/03163-4 - Preparation and characterization of titanium nanoparticles impregnated in carbonanceous materials for application as photocatalysts, BP.TT

Abstract

Will be prepared a high-surface area activated carbon 3D network for utilization as a platform to grow a thin TiO2 nanofilm. It will give rise to optimal photocatalysts based on the Z-scheme heterojunction model, taking advantage of the excellent photocatalytic performance of TiO2, and the superior conversion of light in the confined nanospace of carbon materials. The development of a controlled porous network and well-defined surface chemistry (including a well-dispersed TiO2 film) will provide a bifunctional system able to adsorb and convert simultaneously i) CO2 into value-added chemicals, and ii) water pollutants into harmless compounds. Based on these premises, the main output of the project will be to integrate these components into a single device to get improved photocatalysts for environmentally critical reactions and to be tested under laboratory relevant conditions. The development of extended heterojunctions will provide a charge separation of the photogenerated species, a slow recombination, and the possibility to modulate the light absorption features in the nanoporous cavities of the activated carbon material. On the other hand, the development of high-surface area activated carbon materials to be used as a platform for these Z-heterojunctions will provide a multifunctional system able to achieve an extremely large adsorption/trapping capacity for the target molecules (preferentially in the inner microporous structure), while larger pores, modified with a TiO2 thin film, will act as nanoreactors to convert the adsorbed species into non-toxic or value-added products. The development of this technology is crucial to mitigate CO2 emissions to the atmosphere though CO2 capture and conversion, and to remediate water pollution worldwide. In addition, this technology may decrease or even eliminate the emergent pollutants present in the several effluents. (AU)

Scientific publications

(9)

(The scientific publications listed on this page originate from the Web of Science or SciELO databases. Their authors have cited FAPESP grant or fellowship project numbers awarded to Principal Investigators or Fellowship Recipients, whether or not they are among the authors. This information is collected automatically and retrieved directly from those bibliometric databases.)

SILVA, KAROLINA F.; BRAZIL, TAYRA R.; GIROTO, AMANDA S.; VALENTE, GUSTAVO TARGINO; DOMINGUES, RAQUEL A.; GONCALVES, MARAISA. Activated carbon from agricultural industry waste for use as an adsorbent of sulfamethazine: Fascinating and environmentally friendly process. BIOMASS & BIOENERGY, v. 190, p. 12-pg., 2024-09-19. (19/13471-8)

GLORIA, DIEGO COELHO SANCHES; BRITO, CARLOS HENRIQUE VIEIRA; MENDONCA, THAIS ALINE PRADO; BRAZIL, TAYRA RODRIGUES; DOMINGUES, RAQUEL APARECIDA; VIEIRA, NIRTON CRISTI SILVA; SANTOS, ELIAS BARROS; GONCALVES, MARAISA. Preparation of TiO2/activated carbon nanomaterials with enhanced photocatalytic activity in paracetamol degradation. Materials Chemistry and Physics, v. 305, p. 8-pg., 2023-05-22. (21/02348-0, 19/13471-8)

PORTELA, CAROLINA INACIO; BRAZIL, TAYRA RODRIGUES; MENDONCA, THAIS ALINE PRADO; SANTOS, ELIAS BARROS; DOMINGUES, RAQUEL APARECIDA; VIEIRA, NIRTON CRISTI SILVA; GONCALVES, MARAISA. Activated carbon obtained from coffee husk waste activated by CaCl₂ as support of TiO₂ for the enhanced photocatalytic degradation of Victoria Blue B dye. DIAMOND AND RELATED MATERIALS, v. 139, p. 9-pg., 2023-09-19. (21/02354-0, 19/13471-8)

MENDONCA, THAIS ALINE PRADO; GIROTO, AMANDA SOARES; CHAMBI, JULIAN TICONA; CUFFINI, SILVIA LUCIA; VIEIRA, NIRTON CRISTI SILVA; GONCALVES, MARAISA. Efficient photocatalyst based on activated carbon/graphene oxide/TiO₂ synthesized under acidic conditions for environmental remediation. JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, v. 462, p. 10-pg., 2024-12-29. (19/13471-8)

MEIRELLES, MARIANA R.; OLIVEIRA, CINTHIA C.; SANTOS, ELIAS B.; GONCALVES, MARAISA. Synthesis of titanium dioxide nanoparticles for enhanced photocatalytic activity in the degradation of emerging contaminants. MATERIALS SCIENCE AND ENGINEERING B-ADVANCED FUNCTIONAL SOLID-STATE MATERIALS, v. 306, p. 9-pg., 2024-06-04. (19/13471-8)

PORTELA, CAROLINA INACIO; VIEIRA, NIRTON CRISTI SILVA; BRAZIL, TAYRA RODRIGUES; GIROTO, AMANDA SOARES; GABRIEL FILHO, JOSE BALENA; GONCALVES, MARAISA. Utilization of biodiesel residue through efficient microwave-assisted synthesis of carbon quantum dots: A versatile nanomaterial for environmental remediation. Environmental Research, v. 264, p. 12-pg., 2024-11-14. (19/13471-8, 21/02354-0, 23/10329-1)

MENDONCA, THAIS ALINE PRADO; NASCIMENTO, JOAO PAULO C.; CASAGRANDE, GLEISON ANTONIO; VIEIRA, NIRTON CRISTI SILVA; GONCALVES, MARAISA. Ethylenediamine-modified activated carbon photocatalyst with the highest TiO₂ attachment/dispersion for improved photodegradation of sulfamethazine. Materials Chemistry and Physics, v. 318, p. 10-pg., 2024-03-26. (19/13471-8)

SABINO, SARA PESSOA; SANTOS, ELIAS BARROS; SANTOS, BRENDAH ISABELLY MOREIRA; GONCALVES, MARAISA. Investigation of the photocatalytic activity of various TiO₂ nanoparticles in the contaminant remediation. NEXT MATERIALS, v. 8, p. 8-pg., 2025-07-01. (21/02354-0, 19/13471-8)

BRITO, CARLOS HENRIQUE VIEIRA; GLORIA, DIEGO COELHO SANCHES; SANTOS, ELIAS BARROS; DOMINGUES, RAQUEL APARECIDA; VALENTE, GUSTAVO TARGINO; VIEIRA, NIRTON CRISTI SILVA; GONCALVES, MARAISA. Porous activated carbon/graphene oxide composite for efficient adsorption of pharmaceutical contaminants. CHEMICAL ENGINEERING RESEARCH & DESIGN, v. 191, p. 14-pg., 2023-02-04. (21/02348-0, 19/13471-8)