Development of structured catalysts for the photocatalytic synthesis of ammonia

• Grant number: 23/14214-4
• Support Opportunities: Research Program on Global Climate Change - Regular Grants
• Start date: February 01, 2024
• End date: January 31, 2026
• Field of knowledge: Engineering - Chemical Engineering - Chemical Process Industries
• Principal Investigator: Bruno Ramos
• Grantee: Bruno Ramos
• Host Institution: Centro Universitário FEI (UNIFEI). Campus de São Bernardo do Campo. São Bernardo do Campo , SP, Brazil
• Associated researchers: André Avancini Bernardes ; Andre Luiz da Silva ; Antonio Carlos Silva Costa Teixeira ; Douglas Gouvêa ; Geovânia Cordeiro de Assis ; João Guilherme Rocha Poço ; Juliana Mendonça Silva de Jesus ; Priscila Hasse Palharim ; Rodrigo Condotta ; Rodrigo de Freitas Bueno
• Associated scholarship(s): 24/16830-7 - DEVELOPMENT OF ALTERNATIVE STRUCTURED CATALYSTS FOR THE PROCESS OF PHOTOCATALYTIC SYNTHESIS OF AMMONIA, BP.IC; 24/13525-9 - Development of structured ceramic catalyst supports using robocasting technology, BP.IC

Abstract

The advancement of climate change resulting from the overwhelming increase in CO2 emissions in the atmosphere brought with it the challenge of rethinking the chemical industry in the 21st century. One of the industrial activities with the greatest impact on the generation of greenhouse gases and energy consumption worldwide is the production of ammonia. This project proposes the investigation of production routes for this commodity based on the reduction of nitrogen gas (N2) in the presence of water through series of photochemical reactions in nanostructured catalysts. The project involves two work fronts: the synthesis of modified iron and tungsten oxide nanoparticles; and the preparation of porous ceramic bodies for anchoring these materials, based on titanium and tin oxides. The aim is to deepen the knowledge about the effect of the segregation of defects and dopants, as well as the physicochemical properties of the support materials, on the activity of photocatalysts for the N2 photoreduction process. (AU)

Scientific publications

(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)

ALVES, CATIA ALEXANDRA PODENCE; PALHARIM, PRISCILA HASSE; PRATTO, BRUNA; DA SILVA, ANDRE LUIZ; GOUVEA, DOUGLAS; RAMOS, BRUNO. Photocatalytic ammonia synthesis from nitrogen in water using iron oxides: Comparative efficiency of goethite, magnetite, and hematite. JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, v. 460, p. 11-pg., 2025-03-01. (23/14214-4)

BARBOSA, ANDERSON LUIS; ROMANO, ROBERTO CESAR DE OLIVEIRA; BERNARDES, ANDRE AVANCINI; GOUVEA, DOUGLAS. Rheological and microstructural characterization of titania pastes for additive manufacturing using polymeric ceramic precursor as organic and inorganic binder. CERAMICS INTERNATIONAL, v. 51, n. 17, p. 8-pg., 2025-07-01. (23/14214-4, 20/15230-5)