Development of porous heterogeneous catalysts for the conversion of renewable feedstocks

• Grant number: 10/01449-3
• Support Opportunities: Research Grants - Young Investigators Grants
• Start date: September 01, 2010
• End date: August 31, 2014
• Field of knowledge: Engineering - Chemical Engineering - Chemical Technology
• Principal Investigator: Leandro Pierroni Martins
• Grantee: Leandro Pierroni Martins
• Host Institution: Instituto de Química (IQ). Universidade Estadual Paulista (UNESP). Campus de Araraquara. Araraquara , SP, Brazil
• Associated researchers: Celso Valentim Santilli ; Dilson Cardoso
• Associated scholarship(s): 13/10204-2 - Oxidative dehydration of glycerol to acrylic acid in one step using bifunctional catalysts, BP.DR; 12/08305-2 - Active sites accessibility and catalyst deactivation in the glycerol dehydration using lamellar zeolites, BP.MS; 11/09792-1 - Transformation of glycerol into petrochemical feedstocks catalyzed by different acid zeolites, BP.IC

Abstract

This research project involves a team of one principal researcher and two collaborating researchers, as well as their post graduation and scientific initiation students. Additionally, this project foresees specific scientific initiation and post graduation scholarships. The main theme of this proposal is the use of heterogeneous catalysts with controlled porosity in the conversion of renewable feedstocks. The possibility of obtaining customized solids is extremely interesting in the development of new catalysts and in the comprehension of the physicochemical processes of these materials. The catalysts will be obtained using the combination of organic structure directing agents and the sol-gel process, establishing new synthesis pathways for obtaining aluminosilicates with hierarchical pore structure in the micro-, meso- and macropores scales. The reactions that cover the conversion of renewable feedstocks using heterogeneous porous catalysts and that are included in the scope of this project are alcohols and glycerol conversion into valuable industry feedstocks. The choice for these reactions is because of the availability of these feedstocks and, additionally, the studied catalysts are said to possess acid sites that are suitable for the conversion of the cited feedstocks. (AU)

Scientific publications

(18)

(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)

PASSOS, ALINE RIBEIRO; PULCINELLI, SANDRA HELENA; SANTILLI, CELSO VALENTIM; BRIOIS, VALERIE. Operando monitoring of metal sites and coke evolution during non-oxidative and oxidative ethanol steam reforming over Ni and NiCu ex-hydrotalcite catalysts. CATALYSIS TODAY, v. 336, n. SI, p. 122-130, OCT 1 2019. (10/01449-3, 07/53073-4, 11/08673-9)

VIEIRA, LUIZ H.; CARVALHO, KELE T. G.; URQUIETA-GONZALEZ, ERNESTO A.; PULCINELLI, SANDRA H.; SANTILLI, CELSO V.; MARTINS, LEANDRO. Effects of crystal size, acidity, and synthesis procedure on the catalytic performance of gallium and aluminum MFI zeolites in glycerol dehydration. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, v. 422, n. SI, p. 148-157, OCT 2016. (14/20116-6, 13/01328-0, 10/01449-3)

CASSINELLI, WELLINGTON H.; MARTINS, LEANDRO; MAGNANI, MARINA; PULCINELLI, SANDRA H.; BRIOIS, VALERIE; SANTILLI, CELSO V.. Time-resolved XAS/MS/Raman monitoring of mutual copper self-reduction and ethanol dehydrogenation reactions. RSC ADVANCES, v. 6, n. 25, p. 20453-20457, 2016. (07/53073-4, 10/01449-3, 13/05346-2)

POSSATO, LUIZ G.; CASSINELLI, WELLINGTON H.; MEYER, CAMILO I.; GARETTO, TERESITA; PULCINELLI, SANDRA H.; SANTILLI, CELSO V.; MARTINS, LEANDRO. Thermal treatments of precursors of molybdenum and vanadium oxides and the formed MoxVyOz phases active in the oxydehydration of glycerol. APPLIED CATALYSIS A-GENERAL, v. 532, p. 1-11, FEB 25 2017. (13/10204-2, 10/01449-3)

PAULA, ALEX SILVA; POSSATO, GUSTAVO; RATERO, DAVI RUBINHO; CONTRO, JANINE; KEINAN-ADAMSKY, KEREN; SOARES, RICARDO REIS; GOOBES, GIL; MARTINS, LEANDRO; NERY, JOSE G.. One-step oxidehydration of glycerol to acrylic acid using ETS-10-like vanadosilicates. Microporous and Mesoporous Materials, v. 232, p. 151-160, SEP 15 2016. (11/51851-5, 10/01449-3, 05/54703-6)

PASSOS, ALINE RIBEIRO; LA FONTAINE, CAMILLE; MARTINS, LEANDRO; PULCINELLI, SANDRA HELENA; SANTILLI, CELSO VALENTIM; BRIOIS, VALERIE. Operando XAS/Raman/MS monitoring of ethanol steam reforming reaction-regeneration cycles. CATALYSIS SCIENCE & TECHNOLOGY, v. 8, n. 24, p. 6297-6301, DEC 21 2018. (07/53073-4, 11/08673-9, 10/01449-3)

LUIZ H. VIEIRA; MARIANA V. RODRIGUES; LEANDRO MARTINS. Cristalização convencional de zeólitas e induzida por sementes. Química Nova, v. 37, n. 9, p. 1515-1524, 2014-00-00. (10/01449-3, 12/08305-2)

CASSINELLI, WELLINGTON H.; MARTINS, LEANDRO; PASSOS, ALINE R.; PULCINELLI, SANDRA H.; ROCHET, AMELIE; BRIOIS, VALERIE; SANTILLI, CELSO V.. Correlation between Structural and Catalytic Properties of Copper Supported on Porous Alumina for the Ethanol Dehydrogenation Reaction. CHEMCATCHEM, v. 7, n. 11, p. 1668-1677, JUN 1 2015. (07/53073-4, 10/01449-3, 13/05346-2)

ALVES-ROSA, MARINALVA A.; MARTINS, LEANDRO; HAMMER, PETER; PULCINELLI, SANDRA H.; SANTILLI, CELSO V.. Structure and catalytic properties of sulfated zirconia foams. Journal of Sol-Gel Science and Technology, v. 72, n. 2, p. 8-pg., 2014-11-01. (07/53073-4, 10/01449-3, 12/10215-1)

VIEIRA, LUIZ H.; CARVALHO, KELE T. G.; URQUIETA-GONZALEZ, ERNESTO A.; PULCINELLI, SANDRA H.; SANTILLI, CELSO V.; MARTINS, LEANDRO. Effects of crystal size, acidity, and synthesis procedure on the catalytic performance of gallium and aluminum MFI zeolites in glycerol dehydration. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, v. 422, p. 10-pg., 2016-10-01. (14/20116-6, 13/01328-0, 10/01449-3)

PASSOS, ALINE RIBEIRO; PULCINELLI, SANDRA HELENA; SANTILLI, CELSO VALENTIM; BRIOIS, VALERIE. Operando monitoring of metal sites and coke evolution during non-oxidative and oxidative ethanol steam reforming over Ni and NiCu ex-hydrotalcite catalysts. CATALYSIS TODAY, v. 336, p. 9-pg., 2019-10-01. (07/53073-4, 11/08673-9, 10/01449-3)

POSSATO, LUIZ G.; PEREIRA, ELEN; GONCALVES, ROSEMBERGUE G. L.; PULCINELLI, SANDRA H.; MARTINS, LEANDRO; SANTILLI, CELSO V.. Controlling the porosity and crystallinity of MgO catalysts by addition of surfactant in the sol-gel synthesis. CATALYSIS TODAY, v. 344, n. SI, p. 52-58, MAR 15 2020. (10/01449-3, 16/12752-5)

ALVES-ROSA, MARINALVA A.; MARTINS, LEANDRO; HAMMER, PETER; PULCINELLI, SANDRA H.; SANTILLI, CELSO V.. Structure and catalytic properties of sulfated zirconia foams. Journal of Sol-Gel Science and Technology, v. 72, n. 2, SI, p. 252-259, NOV 2014. (07/53073-4, 12/10215-1, 10/01449-3)

POSSATO, LUIZ G.; CASSINELLI, WELLINGTON H.; GARETTO, TERESITA; PULCINELLI, SANDRA H.; SANTILLI, CELSO V.; MARTINS, LEANDRO. One-step glycerol oxidehydration to acrylic acid on multifunctional zeolite catalysts. APPLIED CATALYSIS A-GENERAL, v. 492, p. 243-251, FEB 25 2015. (13/10204-2, 10/01449-3)

RODRIGUES, MARIANA V.; VIGNATTI, CHARITO; GARETTO, TERESITA; PULCINELLI, SANDRA H.; SANTILLI, CELSO V.; MARTINS, LEANDRO. Glycerol dehydration catalyzed by MWW zeolites and the changes in the catalyst deactivation caused by porosity modification. APPLIED CATALYSIS A-GENERAL, v. 495, p. 84-91, APR 5 2015. (13/01328-0, 12/08305-2, 13/08541-0, 10/01449-3)

PASSOS, ALINE R.; MARTINS, LEANDRO; PULCINELLI, SANDRA H.; SANTILLI, CELSO V.; BRIOIS, VALERIE. Correlation of Sol-Gel Alumina-Supported Cobalt Catalyst Processing to Cobalt Speciation, Ethanol Steam Reforming Activity, and Stability. CHEMCATCHEM, v. 9, n. 20, p. 3918-3929, OCT 23 2017. (07/53073-4, 11/08673-9, 10/01449-3)

PETROLINI, DAVI D.; PULCINELLI, SANDRA H.; SANTILLI, CELSO V.; MARTINS, LEANDRO. Textured macro- and mesoporous alumina samples designed in the presence of different surfactant types. Journal of Sol-Gel Science and Technology, v. 71, n. 1, p. 9-15, JUL 2014. (07/53073-4, 10/01449-3)

POSSATO, LUIZ G.; PEREIRA, ELEN; GONCALVES, ROSEMBERGUE G. L.; PULCINELLI, SANDRA H.; MARTINS, LEANDRO; SANTILLI, CELSO V.. Controlling the porosity and crystallinity of MgO catalysts by addition of surfactant in the sol-gel synthesis. CATALYSIS TODAY, v. 344, p. 7-pg., 2020-03-15. (16/12752-5, 10/01449-3)