Utilization of lignocelulosic and glycerol wastes for production of catalysts with acidic properties

• Grant number: 11/22264-4
• Support Opportunities: Research Grants - Young Investigators Grants
• Start date: August 01, 2013
• End date: July 31, 2016
• Field of knowledge: Physical Sciences and Mathematics - Chemistry
• Principal Investigator: Maraisa Gonçalves
• Grantee: Maraisa Gonçalves
• Host Institution: Instituto de Ciência e Tecnologia (ICT). Universidade Federal de São Paulo (UNIFESP). Campus São José dos Campos. São José dos Campos , SP, Brazil
• Associated researchers: Andréia Silva ; Dalmo Mandelli ; Flávia Camargo Alves Figueiredo ; Mario Cesar Guerreiro ; Nathalia Simone ; Noemia Isoda ; Raphael Rodrigues ; Thalita Soares Galhardo ; Wagner Alves Carvalho
• Associated scholarship(s): 14/18529-0 - Preparation of activated carbon with high surface area from biodiesel waste, BP.JP

Abstract

In recent years, alternatives to minimize the continuous increase in environmental pollution are being carefully studied. In Brazil, agro industries and biodiesel production generates a great amount of waste, thus, demanding researches on conversion of these wastes into higher added value materials. These strategies include the production of acidity carbon and activated carbon (AC) from agro-industrial residues and biodiesel byproduct and to apply it as catalyst for glycerol etherification with tert-butanol or isobutene. Based on the literature and earlier works, of AC will be prepared as to obtain a unique characteristic: high micro mesoporosity. In addition, a surface treatment with HNO3 and H2SO4 will be applied for insertion of acid groups, and finally its activity as catalyst in the etherification reaction of glycerol will be evaluated. This new catalyst will have its catalytic activity compared to existing commercial catalysts, such as Amberlyst, and also to literature data. (AU)

Scientific publications

(11)

(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)

ISODA, NOEMIA; RODRIGUES, RAPHAEL; SILVA, ANDREIA; GONCALVES, MARAISA; MANDELLI, DALMO; FIGUEIREDO, FLAVIA CAMARGO A.; CARVALHO, WAGNER ALVES. Optimization of preparation conditions of activated carbon from agriculture waste utilizing factorial design. Powder Technology, v. 256, p. 175-181, APR 2014. (11/14626-3, 11/22264-4)

CELDEIRA, PATRICIA A.; GONCALVES, MARAISA; FIGUEIREDO, FLDVIA C. A.; DAL BOSCO, SANDRA MARIA; MANDELLI, DALMO; CARVALHO, WAGNER A.. Sulfonated niobia and pillared clay as catalysts in etherification reaction of glycerol. APPLIED CATALYSIS A-GENERAL, v. 478, p. 98-106, MAY 20 2014. (09/07125-8, 11/14626-3, 11/22264-4)

GONCALVES, MARAISA; RODRIGUES, RAPHAEL; GALHARDO, THALITA S.; CARVALHO, WAGNER A.. Highly selective acetalization of glycerol with acetone to solketal over acidic carbon-based catalysts from biodiesel waste. FUEL, v. 181, p. 46-54, OCT 1 2016. (11/22264-4, 13/21160-6, 14/18529-0)

MICHELLE MANTOVANI; ERIK MODA AGUIAR; WAGNER ALVES CARVALHO; DALMO MANDELLI; MARAISA GONÇALVES. APROVEITAMENTO DE RESÍDUO DE BIODIESEL PARA PREPARAÇÃO DE CARVÕES ÁCIDOS COM ELEVADA ATIVIDADE CATALÍTICA NA REAÇÃO DE ETERIFICAÇÃO DO GLICEROL. Química Nova, v. 38, n. 4, p. 526-532, 2015-05-00. (13/21160-6, 11/22264-4, 14/18529-0)

GONCALVES, MARAISA; CASTRO, CINTHIA S.; OLIVEIRA, LUIZ C. A.; CARVALHO, WAGNER A.. Green acid catalyst obtained from industrial wastes for glycerol etherification. Fuel Processing Technology, v. 138, p. 695-703, OCT 2015. (11/22264-4, 13/21160-6, 14/18529-0)

GONCALVES, MARAISA; SOLER, FELIPE COELHO; ISODA, NOEMIA; CARVALNO, WAGNER ALVES; MANDELLI, DALMO; SEPULVEDA, JORGE. Glycerol conversion into value-added products in presence of a green recyclable catalyst: Acid black carbon obtained from coffee ground wastes. Journal of the Taiwan Institute of Chemical Engineers, v. 60, p. 294-301, MAR 2016. (11/22264-4, 13/21160-6, 14/18529-0)

SILVA, CAUE A. C.; FIGUEIREDO, FLAVIA C. A.; RODRIGUES, RAPHAEL; SAIRRE, MIRELA I.; GONCALVES, MARAISA; MATOS, INES; FONSECA, ISABEL M.; MANDELLI, DALMO; CARVALHO, WAGNER A.. Enhancing the biodiesel manufacturing process by use of glycerin to produce hyacinth fragrance. Clean Technologies and Environmental Policy, v. 18, n. 5, SI, p. 1551-1563, JUN 2016. (11/22264-4)

JORGE SEPÚLVEDA; DEBORA MANUALE; LUCIA SANTIAGO; NICOLÁS CARRARA; GERARDO TORRES; CARLOS VERA; MARAISA GONCALVES; WAGNER CARVALHO; DALMO MANDELLI. SELECTIVE HYDROGENOLYSIS OF GLYCEROL TO PROPYLENE GLYCOL IN A CONTINUOUS FLOW TRICKLE BED REACTOR USING COPPER CHROMITE AND Cu/Al2O3 CATALYSTS. Química Nova, v. 40, n. 4, p. 371-377, 2017-05-00. (11/22264-4)

GONCALVES, MARAISA; MANTOVANI, MICHELLE; CARVALHO, WAGNER ALVES; RODRIGUES, RAPHAEL; MANDELLI, DALMO; ALBERO, JOAQUIN SILVESTRE. Biodiesel wastes: An abundant and promising source for the preparation of acidic catalysts for utilization in etherification reaction. CHEMICAL ENGINEERING JOURNAL, v. 256, p. 468-474, NOV 15 2014. (11/14626-3, 11/22264-4)

RODRIGUES, RAPHAEL; GONCALVES, MARAISA; MANDELLI, DALMO; PESCARMONA, PAOLO P.; CARVALHO, WAGNER A.. Solvent-free conversion of glycerol to solketal catalysed by activated carbons functionalised with acid groups. CATALYSIS SCIENCE & TECHNOLOGY, v. 4, n. 8, p. 2293-2301, 2014. (11/14626-3, 11/22264-4)

SILVA, CAUE A. C.; FIGUEIREDO, FLAVIA C. A.; RODRIGUES, RAPHAEL; SAIRRE, MIRELA I.; GONCALVES, MARAISA; MATOS, INES; FONSECA, ISABEL M.; MANDELLI, DALMO; CARVALHO, WAGNER A.. Enhancing the biodiesel manufacturing process by use of glycerin to produce hyacinth fragrance. Clean Technologies and Environmental Policy, v. 18, n. 5, p. 13-pg., 2016-06-01. (11/22264-4)