Organic and inorganic systems for obtaining of meso and nanostructures

• Grant number: 17/13839-0
• Support Opportunities: Regular Research Grants
• Start date: February 01, 2018
• End date: January 31, 2020
• Field of knowledge: Engineering - Chemical Engineering - Chemical Technology
• Principal Investigator: Eduardo Rezende Triboni
• Grantee: Eduardo Rezende Triboni
• Host Institution: Escola de Engenharia de Lorena (EEL). Universidade de São Paulo (USP). Lorena , SP, Brazil
• City of the host institution: Lorena
• Associated researchers: Dayane Batista Tada ; Fabiane de Jesus Trindade ; Fábio Herbst Florenzano ; Fábio Rodolfo Miguel Batista ; Grégoire Jean-François Demets ; Rebeca Bacani

Abstract

Meso- and nanostructured systems receive a lot of attention because of the improved performance they bring to the areas in which are applied. Within this context, methods of preparation aiming at certain structural arrangements, or structures designed to achieve some specific function and property, play a fundamental role in the development of new materials. The present proposal deals with the evolution of the line of research that has been developing in the laboratory of Photochemistry and Functional Materials - EEL/USP. The subjects involved in this proposal are: i. the scale up and diversification of the Glycerol-Urea route (patent number BR 10 2017 011345-0) for the production of new nanostructured systems; ii. development of core-shell systems between metal oxides and metals (MO/Metal) for studies and photocatalytic application aiming at production of hydrogen through water-spliting and photodegradation of organic substrates; iii. synthesis and characterization of organogels and organic crystals based on semiconducting organic molecules with self-assembly capacity. Analytical methods and mathematical modeling will be developed for the elucidation of synthetic mechanisms. (AU)

Scientific publications

(9)

(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)

RODRIGUES, BRUNO V. M.; CABRAL, TAYNA S.; SGOBBI, LIVIA F.; DELEZUK, JORGE A. M.; PESSOA, RODRIGO S.; TRIBONI, EDUARDO R.; DE MORAES, THAISA B. F.; LOBO, ANDERSON O.. A simple and green method for the production of nanostructured materials from poly(vinyl alcohol)/graphene quantum dots. Materials Chemistry and Physics, v. 219, p. 242-250, NOV 1 2018. (11/17877-7, 13/08166-5, 15/08523-8, 17/13839-0, 17/18826-3)

CASTANHEIRA, BRUNA; TRIBONI, EDUARDO RESENDE; ANDRADE, LUANA DOS SANTOS; TRINDADE, FABIANE DE JESUS; OTUBO, LARISSA; SILVA COSTA TEIXEIRA, ANTONIO CARLOS; POLITI, MARIO JOSE; DE QUEIROZ, THIAGO BRANQUINHO; BROCHSZTAIN, SERGIO. Synthesis of Novel Periodic Mesoporous Organosilicas Containing 1,4,5,8-Naphthalenediimides within the Pore Walls and Their Reduction To Generate Wall-Embedded Free Radicals. Langmuir, v. 34, n. 28, p. 8195-8204, JUL 17 2018. (17/13839-0, 15/06064-6, 16/05496-2)

SA, ALEXANDRO S.; FEITOSA, RODRIGO P.; HONORIO, LUZIA; PENA-GARCIA, RAMON; ALMEIDA, LUCIANO C.; DIAS, JULIANA S.; BRAZUNA, LORENA P.; TABUTI, THIAGO G.; TRIBONI, EDUARDO R.; OSAJIMA, JOSY A.; et al. Brief Photocatalytic Study of ZnO Containing Cerium towards Ibuprofen Degradatio. MATERIALS, v. 14, n. 19, OCT 2021. (17/13839-0)

SILVA, FRANCISCO DE ARAUJO; CICOLANI, RENATO SALVIATO; LIMA, GILBERTO; HUGUENIN, FRITZ; DEMETS, GREGOIRE JEAN-FRANCOIS. Enhanced Li+ charge storage in naphthalene diimide/vanadium pentoxide intercalates. RSC ADVANCES, v. 8, n. 42, p. 24029-24035, 2018. (17/19595-5, 16/12666-1, 17/13839-0)

BRAZUNA, LORENA PORTELA; TABUTI, THIAGO GALEOTE; SILVA, ADRIELLE DE PAULA; TADA, DAYANE BATISTA; POLITI, MARIO JOSE; BACANI, REBECA; TRIBONI, EDUARDO REZENDE. Effect of lithium and sodium ions on the size and morphology of ZnO nanoparticles synthesized by a glycerol-urea route. NEW JOURNAL OF CHEMISTRY, v. 43, n. 48, p. 18988-18995, DEC 28 2019. (17/13839-0, 13/08166-5, 17/01697-6)

MORAES, THAISA B. F.; SCHIMIDT, MARCOS F. R. A.; BACANI, REBECA; WEBER, GABRIEL; POLITI, MARIO J.; CASTANHEIRA, BRUNA; BROCHSZTAIN, SERGIO; SILVA, FRANCISCO DE A.; DEMETS, GREGOIRE J-F; TRIBONI, EDUARDO R.. Polysilsesquioxane naphthalenediimide thermo and photochromic gels. Journal of Luminescence, v. 204, p. 685-691, DEC 2018. (15/06064-6, 13/07937-8, 16/12666-1, 13/08166-5, 16/05496-2, 17/13839-0)

SCHIMIDT, MARCOS F. R. A.; JUNQUEIRA, HELENA C.; PEDRAS, BRUNO; BERBERAN-SANTOS, MARIO N.; TRIBONI, EDUARDO R.; FLORENZANO, FABIO H.. Charge transfer emission from 1,4,5,8-naphthalimide-polystyrene. MATERIALS SCIENCE AND ENGINEERING B-ADVANCED FUNCTIONAL SOLID-STATE MATERIALS, v. 266, APR 2021. (17/13839-0, 13/08166-5)

SILVA, LAYANE A. L.; SILVA, ANDRE A. L.; RIOS, MARIA A. S.; BRITO, MANOEL P.; ARAUJO, ALYNE R.; SILVA, DURCILENE A.; PENA-GARCIA, RAMON R.; SILVA-FILHO, EDSON C.; MAGALHAES, JANILDO L.; MATOS, JOSE M. E.; et al. Insights into the Antimicrobial Activity of Hydrated Cobaltmolybdate Doped with Copper. Molecules, v. 26, n. 5, MAR 2021. (17/13839-0)

DIAS, J. S.; BATISTA, F. R. M.; BACANI, R.; TRIBONI, E. R.. Structural characterization of SnO nanoparticles synthesized by the hydrothermal and microwave routes. SCIENTIFIC REPORTS, v. 10, n. 1, JUN 10 2020. (17/13839-0, 13/08166-5, 16/17708-4)

Filed patent(s) as a result of this research project