Electrocatalysis of the hydrogen oxidation reaction and sodium borohydride on dispersed catalysts formed by AB5-type metal hydride alloys

• Grant number: 12/09109-2
• Support Opportunities: Scholarships in Brazil - Doctorate (Direct)
• Start date: July 01, 2012
• End date: February 29, 2016
• Field of knowledge: Physical Sciences and Mathematics - Chemistry - Physical-Chemistry
• Principal Investigator: Edson Antonio Ticianelli
• Grantee: Waldemir José Paschoalino Junior
• Host Institution: Instituto de Química de São Carlos (IQSC). Universidade de São Paulo (USP). São Carlos , SP, Brazil
• Associated research grant: 09/07629-6 - Electrocatalysis IV: fundamental and applied aspects of electrocatalytic processes, bio-electrocatalysis and kinetic instabilities, AP.BIOEN.TEM
• Associated scholarship(s): 12/21835-0 - Electrocatalysis of sodium borohydride oxidation reaction on dispersed catalysts formed by AB5-type metal hydride alloys, BE.EP.DD

Abstract

In this work it will be conducted activities of research and development of electrocatalysts formed Pt and/or Pd nanoparticles supported on a metal hydride alloys, for ultimate use on alkaline fuel cell anodes. The aim is to develop a product presenting hydrogen storage capacity, in the form of hydride, by exposition to gaseous hydrogen or sodium borohydride, and whose anodic process being either the molecular hydrogen oxidation and the absorbed hydride oxidation. (AU)

Scientific publications

(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)

PASCHOALINO, WALDEMIR J.; THOMPSON, STEPHEN J.; RUSSELL, ANDREA E.; TICIANELLI, EDSON A.. The Borohydride Oxidation Reaction on La-Ni-Based Hydrogen-Storage Alloys. ChemPhysChem, v. 15, n. 10, p. 7-pg., 2014-07-21. (12/09109-2, 12/21835-0)

PASCHOALINO, WALDEMIR J.; THOMPSON, STEPHEN J.; RUSSELL, ANDREA E.; TICIANELLI, EDSON A.. The Borohydride Oxidation Reaction on La-Ni-Based Hydrogen-Storage Alloys. ChemPhysChem, v. 15, n. 10, SI, p. 2170-2176, JUL 21 2014. (12/21835-0, 12/09109-2)

Academic Publications

(References retrieved automatically from State of São Paulo Research Institutions)

PASCHOALINO JUNIOR, Waldemir José. Electrocatalysis of the Hydrogen Oxidation Reaction and Sodium Borohydride on Dispersed Catalysts Formed by AB5-type Metal Hydride Alloys. 2016. Doctoral Thesis - Universidade de São Paulo (USP). Instituto de Química de São Carlos (IQSC/BT) São Carlos.