VAPOR-LIQUID EQUILIBRIUM OF SYSTEMS PRESENT IN THE PRODUCTION BY CHEMICAL PROCESS OF 2,5-DIMETHYIL FURAN FROM BIOMASS

• Grant number: 12/09646-8
• Support Opportunities: Scholarships in Brazil - Post-Doctorate
• Effective date (Start): November 01, 2012
• Effective date (End): March 31, 2015
• Field of knowledge: Engineering - Chemical Engineering - Chemical Process Industries
• Principal Investigator: Aline Carvalho da Costa
• Grantee: Luis Alberto Follegatti Romero
• Host Institution: Faculdade de Engenharia Química (FEQ). Universidade Estadual de Campinas (UNICAMP). Campinas , SP, Brazil

Abstract

Recently, an increasing effort has been devoted to the search of new self-sustainable liquid biofuels that allow overcome some limitations of ethanol, such as, low energy density, high volatility and contamination by the absorption of water from the atmosphere. 2,5-dimethylfuran (DMF) is a heterocyclic compound that can be used as liquid fuel and shows superior characteristics when compared to ethanol. The DMF production process starts with the acid-catalysed dehydration of fructose (a carbohydrate obtained directly from biomass) to produce 5-hydroxymethylfurfural (HMF) in a biphasic reactor, followed by separation, conversion and purification steps. The separation and purification steps require a deep knowledge of the liquid-vapor phase equilibrium behavior. Determination of vapor-liquid equilibrium data (VLE) and thermodynamic modeling allow characterize and describe the phase behavior of a system and they are also needed to design, model and simulate a DMF production plant in order to energy saving and reduce equipment costs. The objective of this project is determining experimentally the liquidvapor equilibrium data for binary systems containing: HMF + water/HCl; DMF + 2-methylfuran and DMF + water and the ternary system composed of 2-methylfuran + DMF + water at 90, 100, 120 ºC. The VLE data will be submitted to thermodynamic consistency test and correlated using activity coefficients models for the liquid phase: Wilson, UNIQUAC and/or NRTL equations, while, for the vapor phase, the fugacity coefficient will be calculated using the VIRIAL equation.

Scientific publications

(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)

DE AZEVEDO ROCHA, ENIO G.; FOLLEGATTI-ROMERO, LUIS A.; DUVOISIN, JR., SERGIO; AZNAR, MARTIN. Liquid-liquid equilibria for ternary systems containing ethylic palm oil biodiesel plus ethanol plus glycerol/water: Experimental data at 298.15 and 323.15 K and thermodynamic modeling. FUEL, v. 128, p. 356-365, JUL 15 2014. (12/09646-8)

T. P. V. B. DIAS; P. MIELKE NETO; M. ANSOLIN; L. A. FOLLEGATTI-ROMERO; E. A. C. BATISTA; A. J. A. MEIRELLES. LIQUID-LIQUID EQUILIBRIUM FOR TERNARY SYSTEMS CONTAINING ETHYLIC BIODIESEL + ANHYDROUS ETHANOL + REFINED VEGETABLE OIL (SUNFLOWER OIL, CANOLA OIL AND PALM OIL): EXPERIMENTAL DATA AND THERMODYNAMIC MODELING. Brazilian Journal of Chemical Engineering, v. 32, n. 3, p. 699-706, 2015-09-00. (08/56258-8, 12/09646-8)

DIAS, T. P. V. B.; NETO, P. MIELKE; ANSOLIN, M.; FOLLEGATTI-ROMERO, L. A.; BATISTA, E. A. C.; MEIRELLES, A. J. A.. LIQUID-LIQUID EQUILIBRIUM FOR TERNARY SYSTEMS CONTAINING ETHYLIC BIODIESEL plus ANHYDROUS ETHANOL plus REFINED VEGETABLE OIL (SUNFLOWER OIL, CANOLA OIL AND PALM OIL): EXPERIMENTAL DATA AND THERMODYNAMIC MODELING. Brazilian Journal of Chemical Engineering, v. 32, n. 3, p. 699-706, JUL-SEP 2015. (12/09646-8, 08/56258-8)