Development of silica-based mesoporous materials from biomass for use as remediation system for polycyclic aromatic hydrocarbon (PAH's)

• Grant number: 14/05679-4
• Support Opportunities: Scholarships in Brazil - Doctorate
• Start date until: June 01, 2014
• End date until: July 31, 2017
• Field of knowledge: Engineering - Materials and Metallurgical Engineering - Nonmetallic Materials
• Agreement: Coordination of Improvement of Higher Education Personnel (CAPES)
• Principal Investigator: Caio Marcio Paranhos da Silva
• Grantee: José Arnaldo Santana Costa
• Host Institution: Centro de Ciências Exatas e de Tecnologia (CCET). Universidade Federal de São Carlos (UFSCAR). São Carlos , SP, Brazil
• Associated research grant: 13/07296-2 - CDMF - Center for the Development of Functional Materials, AP.CEPID

Abstract

Polycyclic aromatic hydrocarbons (PAH 's) are internationally recognized as one of the most degrading and polluting substances originating from industrial economic cycle. Several international and national environmental agencies have produced extensive literature on the harmful and potentially fatal consequences of human exposure to PAH 's. Various methods have been investigated in the context of remediation ability of PAH 's from the use of absorbent materials . Recently, the use of absorbent materials with micro / nano dimensions has shown potential, mainly due to the high surface area and the possibility of chemical decoration of the surface of these materials. However, most of the research works using this material indicates low regenerative capacity, i.e., the ability to reuse the material for absorbing PAH 's. In this project, remediation ability of silica-based absorbent micro/nanoparticles extracted from biomass will be systematically studied in terms of the method of preparation and surface chemistry decoration. The aim is to achieve low cost absorbent and economically sustainable systems. Moreover, the regenerative capacity will be evaluated from the insertion of these materials in polymeric membranes, a novel approach for the remediation of PAH 's. Besides the regenerative capacity, a systematic study of the transport properties of these membranes HPA 's will be performed . (AU)

Scientific publications

(11)

(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)

COSTA, JOSE ARNALDO S.; SARMENTO, VICTOR H. V.; ROMAO, LUCIANE P. C.; PARANHOS, CAIO M.. Removal of polycyclic aromatic hydrocarbons from aqueous media with polysulfone/MCM-41 mixed matrix membranes. JOURNAL OF MEMBRANE SCIENCE, v. 601, MAR 1 2020. (17/06775-5, 14/05679-4, 13/07296-2)

COSTA, JOSE ARNALDO SANTANA; VEDOVELLO, PRISCILA; PARANHOS, CAIO MARCIO. Use of Ionic Liquid as Template for Hydrothermal Synthesis of the MCM-41 Mesoporous Material. SILICON, v. 12, n. 2, p. 289-294, FEB 2020. (15/00609-0, 17/06775-5, 18/18894-1, 14/05679-4, 13/07296-2)

SANTANA COSTA, JOSE ARNALDO; PARANHOS, CAIO MARCIO. Evaluation of rice husk ash in adsorption of Remazol Red dye from aqueous media. SN APPLIED SCIENCES, v. 1, n. 5, MAY 2019. (18/18894-1, 14/05679-4, 17/06775-5, 13/07296-2)

COSTA, JOSE ARNALDO S.; SARMENTO, VICTOR H. V.; ROMAO, LUCIANE P. C.; PARANHOS, CAIO M.. Synthesis of functionalized mesoporous material from rice husk ash and its application in the removal of the polycyclic aromatic hydrocarbons. Environmental Science and Pollution Research, v. 26, n. 25, p. 25476-25490, SEP 2019. (18/18894-1, 14/05679-4, 17/06775-5, 13/07296-2)

COSTA, JOSE ARNALDO S.; DE JESUS, ROBERTA A.; DORST, DIANE D.; PINATTI, IVO M.; OLIVEIRA, LUCAS M. DA R.; DE MESQUITA, MARIA E.; PARANHOS, CAIO MARCIO. Photoluminescent properties of the europium and terbium complexes covalently bonded to functionalized mesoporous material PABA-MCM-41. Journal of Luminescence, v. 192, p. 1149-1156, DEC 2017. (14/05679-4, 13/23995-8)

SANTANA COSTA, JOSE ARNALDO; PARANHOS, CAIO MARCIO. Systematic evaluation of amorphous silica production from rice husk ashes. JOURNAL OF CLEANER PRODUCTION, v. 192, p. 688-697, AUG 10 2018. (14/05679-4, 13/07296-2)

SANTANA COSTA, JOSE ARNALDO; DE JESUS, ROBERTA ANJOS; PARANHOS DA SILVA, CAIO MARCIO; CRUZ ROMAO, LUCIANE PIMENTA. Efficient adsorption of a mixture of polycyclic aromatic hydrocarbons (PAHs) by Si-MCM-41 mesoporous molecular sieve. Powder Technology, v. 308, p. 434-441, FEB 15 2017. (14/05679-4)

COSTA, JOSE ARNALDO S.; SARMENTO, VICTOR H. V.; ROMAO, LUCIANE P. C.; PARANHOS, CAIO M.. Adsorption of organic compounds on mesoporous material from rice husk ash (RHA). BIOMASS CONVERSION AND BIOREFINERY, v. 10, n. 4, p. 1105-1120, DEC 2020. (18/18894-1, 14/05679-4, 17/06775-5, 13/07296-2)

COSTA, JOSE ARNALDO S.; DE JESUS, ROBERTA A.; SANTOS, DANILO O.; MANO, JOAO F.; ROMAO, LUCIANE P. C.; PARANHOS, CAIO M.. Recent progresses in the adsorption of organic, inorganic, and gas compounds by MCM-41-based mesoporous materials. Microporous and Mesoporous Materials, v. 291, JAN 1 2020. (18/18894-1, 14/05679-4, 17/06775-5, 13/07296-2)

COSTA, JOSE A. S.; SARMENTO, VICTOR H. V.; ROMAO, LUCIANE P. C.; PARANHOS, CAIO M.. Performance of the MCM-41-NH2 Functionalized Mesoporous Material Synthetized from the Rice Husk Ash on the Removal of the Polycyclic Aromatic Hydrocarbons. SILICON, v. 12, n. 8, NOV 2019. (18/18894-1, 14/05679-4, 17/06775-5, 13/07296-2)

COSTA, JOSE ARNALDO S.; PARANHOS, CAIO M.. Mitigation of silica-rich wastes: An alternative to the synthesis eco-friendly silica-based mesoporous materials. Microporous and Mesoporous Materials, v. 309, p. 16-pg., 2020-12-15. (18/18894-1, 14/05679-4, 13/07296-2, 17/06775-5)