Solution-processed charge-transport layers for efficient perovskite solar cells

• Grant number: 18/05152-7
• Support Opportunities: Scholarships abroad - Research Internship - Post-doctor
• Start date until: August 01, 2018
• End date until: July 31, 2019
• Field of knowledge: Physical Sciences and Mathematics - Physics - Condensed Matter Physics
• Principal Investigator: Andrea Simone Stucchi de Camargo Alvarez Bernardez
• Grantee: Kassio Papi da Silva Zanoni
• Supervisor: Henk J. Bolink
• Host Institution: Instituto de Física de São Carlos (IFSC). Universidade de São Paulo (USP). São Carlos , SP, Brazil
• Institution abroad: Universitat de València, Spain
• Associated to the scholarship: 16/07706-4 - Nanocrystalline luminescent materials: new chemical concepts for energy conversion and sustainability, BP.PD

Abstract

Perovskite solar cells (PSCs) have attracted great interest for rapidly growing light-to-electricity conversion efficiencies, already exceeding 22%, although they still lack high stability, especially in air and humidity. In this project, novel solution-processed oxide semiconductor materials will be prepared and characterized towards applications as hole- and/or electron-transport layers (HTL and ETL, respectively) in PSCs with enhanced efficiencies and stability.p-type (NiO, MoO3, V2O5 and/or graphene oxide) and n-type (TiO2 and/or ZnO) oxide semiconductors with desired band energies will be prepared via solution-processed methods. These materials will be deposited as thin films via solution-processed techniques, in special layer-by-layer (LbL) structures, with optimal electric, optical and morphological characteristics for applications as HTLs and/or ETLs in optoelectronic devices. PSCs will be fabricated in two different configurations employing a vacuum-assisted deposition of the active perovskite layer and the developed solution-processed HTLs and/or ETLs. The behavior and stability of the PSCs having the developed transport thin layers will be evaluated to elucidate the charge extraction effectiveness of the novel compact films. (AU)

Scientific publications

(9)

(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)

BABAEI, AZIN; ZANONI, KASSIO P. S.; GIL-ESCRIG, LIDON; PEREZ-DEL-REY, DANIEL; BOIX, PABLO P.; SESSOLO, MICHELE; BOLINK, HENK J.. Efficient Vacuum Deposited P-I-N Perovskite Solar Cells by Front Contact Optimization. FRONTIERS IN CHEMISTRY, v. 7, JAN 17 2020. (18/05152-7)

ZANONI, KASSIO P. S.; VILELA, RAQUEL R. C.; SILVA, IGOR D. A.; MURAKAMI IHA, NEYDE Y.; ECKERT, HELLMUT; DE CAMARGO, ANDREA S. S.. Photophysical Properties of Ir(III) Complexes Immobilized in MCM-41 via Templated Synthesis. Inorganic Chemistry, v. 58, n. 8, p. 4962-4971, APR 15 2019. (16/07706-4, 13/07793-6, 18/05152-7)

NORTON, AMIE E.; ZANONI, KASSIO P. S.; DOURGES, MARIE-ANNE; RAVARO, LEANDRO P.; ABDOLMALEKI, MAHMOOD K.; DE CAMARGO, ANDREA S. S.; TOUPANCE, THIERRY; CONNICK, WILLIAM B.; CHATTERJEE, SAYANDEV. Porosity induced rigidochromism in platinum(ii) terpyridyl luminophores immobilized at silica composites. JOURNAL OF MATERIALS CHEMISTRY C, v. 9, n. 19, APR 2021. (18/05152-7, 16/07706-4, 13/07793-6)

NEUKOM, MARTIN T.; SCHILLER, ANDREAS; ZUFLE, SIMON; KNAPP, EVELYNE; AVILA, JORGE; PEREZ-DEL-REY, DANIEL; DREESSEN, CHRIS; ZANONI, KASSIO P. S.; SESSOLO, MICHELE; BOLINK, HENK J.; et al. Consistent Device Simulation Model Describing Perovskite Solar Cells in Steady-State, Transient, and Frequency Domain. ACS APPLIED MATERIALS & INTERFACES, v. 11, n. 26, p. 23320-23328, JUL 3 2019. (18/05152-7)

ZANONI, KASSIO P. S.; PEREZ-DEL-REY, DANIEL; DREESSEN, CHRIS; ANGELES HERNANDEZ-FENOLLOSA, MA; DE CAMARGO, ANDREA S. S.; SESSOLO, MICHELE; BOIX, PABLO P.; BOLINK, HENK J.. Use of Hydrogen Molybdenum Bronze in Vacuum-Deposited Perovskite Solar Cells. ENERGY TECHNOLOGY, v. 8, n. 4, p. 4-pg., 2019-09-25. (13/07793-6, 18/05152-7)

ZANONI, KASSIO P. S.; PEREZ-DEL-REY, DANIEL; DREESSEN, CHRIS; ANGELES HERNANDEZ-FENOLLOSA, MA; DE CAMARGO, ANDREA S. S.; SESSOLO, MICHELE; BOIX, PABLO P.; BOLINK, HENK J.. Use of Hydrogen Molybdenum Bronze in Vacuum-Deposited Perovskite Solar Cells. ENERGY TECHNOLOGY, v. 8, n. 4, SI, SEP 2019. (13/07793-6, 18/05152-7)

BABAEI, AZIN; ZANONI, KASSIO P. S.; GIL-ESCRIG, LIDON; PEREZ-DEL-REY, DANIEL; BOIX, PABLO P.; SESSOLO, MICHELE; BOLINK, HENK J.. Efficient Vacuum Deposited P-I-N Perovskite Solar Cells by Front Contact Optimization. RONTIERS IN CHEMISTR, v. 7, p. 6-pg., 2020-01-17. (18/05152-7)

ZANONI, KASSIO P. S.; RAVARO, LEANDRO P.; DE CAMARGO, ANDREA S. S.. Host-guest luminescent materials based on highly emissive species loaded into versatile sol-gel hosts. DALTON TRANSACTIONS, v. 47, n. 37, p. 12813-12826, OCT 7 2018. (16/17495-0, 13/24727-7, 16/07706-4, 13/07793-6, 18/05152-7)

PEREZ-DEL-REY, DANIEL; GIL-ESCRIG, LIDON; ZANONI, KASSIO P. S.; DREESSEN, CHRIS; SESSOLO, MICHELE; BOIX, PABLO P.; BOLINK, HENK J.. Molecular Passivation of MoO3 : Band Alignment and Protection of Charge Transport Layers in Vacuum-Deposited Perovskite Solar Cells. CHEMISTRY OF MATERIALS, v. 31, n. 17, p. 6945-6949, SEP 10 2019. (18/05152-7)