Interactions of nutrients with humic material extracted from process water of sugarcane bagasse with vinasse hydrothermal carbonization

• Grant number: 18/05673-7
• Support Opportunities: Scholarships in Brazil - Scientific Initiation
• Start date: August 01, 2018
• End date: November 03, 2020
• Field of knowledge: Physical Sciences and Mathematics - Chemistry - Analytical Chemistry
• Principal Investigator: Altair Benedito Moreira
• Grantee: Vinicius Sarracini Santos
• Host Institution: Instituto de Biociências, Letras e Ciências Exatas (IBILCE). Universidade Estadual Paulista (UNESP). Campus de São José do Rio Preto. São José do Rio Preto , SP, Brazil
• Associated scholarship(s): 19/18831-2 - Humic-like substances from process water: complexation capacity and characterization using molecular fluorescence, BE.EP.IC

Abstract

The humic substances (HS) are macromolecular components resulting from chemical and biological degradation of vegetal and animal residues. It are widely distributed in soils, natural waters and sediments. Studies demonstrated that hydrotermic carbonization of biomass makes a carbon recalcitrant rich material, denomitated hydrotermal coal and a liquid fase denominated process water. The process uses mild temperatures of at most 300°C, humid biomass and self-generated pressure. The process water presents high quantities of organic matter and some nutrients. This project aims to characterize and study a complexant capacitie of "humic material", extracted from process water with metals copper and aluminium.This project the HTC will be made using the subproducts of sugarcane sector, the sugarcane bagasse and the vinasse. The carbonization will be realized in 232°C using a misture of sugarcane bagass and vinasse with addition of 1 and 4 percent of sulfuric acid. The humic material will be extracted following the recomendations of International Society of Humic Substances. The humic material extracted from process water will be characterized in elementar analysis (CHNS), concentration of total organical carbon (TOC) analysis, ultraviolet-visible spectroscopy, molecular fluorescence and nuclear magnetic resonance (NMR) (AU)

Scientific publications

(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)

SANTOS, VINICIUS S.; MOURA, BERNARDO R.; CONSTANTINO, ISABELA C.; METZKER, GUSTAVO; BOSCOLO, MAURICIO; CORNELIO, MARINONIO L.; FERREIRA, ODAIR P.; MOUNIER, JEAN L. S.; HAJJOUL, HOUSSAM; BISINOTI, MARCIA C.; et al. helating properties of humic-like substances obtained from process water of hydrothermal carbonizatio. ENVIRONMENTAL TECHNOLOGY & INNOVATION, v. 23, AUG 2021. (18/05673-7, 17/26718-6)

MOURA, BERNARDO R.; SANTOS, VINICIUS S.; METZKER, GUSTAVO; FERREIRA, ODAIR P.; BISINOTI, MARCIA C.; BOSCOLO, MAURICIO; MOREIRA, ALTAIR B.. Oxidation of hydrochar produced from byproducts of the sugarcane industry for the production of humic-like substances: Characterization and interaction study with Cu(II). Chemosphere, v. 324, p. 8-pg., 2023-03-08. (18/05673-7, 17/26718-6, 19/18831-2, 18/15733-7, 19/17918-7, 10/09998-6)

SANTOS, VINICIUS S.; MOURA, BERNARDO R.; METZKER, GUSTAVO; CORNELIO, MARINONIO L.; FERREIRA, ODAIR P.; MOUNIER, STEPHANE J. L.; HAJJOUL, HOUSSAM; BOSCOLO, MAURICIO; BISINOTI, MARCIA C.; MOREIRA, ALTAIR B.. Increase of Fluorescence of Humic-Like Substances in Interaction with Cd(II): a Photoinduced Charge Transfer Approach. Journal of Fluorescence, v. N/A, p. 7-pg., 2022-06-09. (18/05673-7, 21/09126-3, 10/09998-6, 14/22400-3, 19/18831-2, 18/15733-7, 17/26718-6, 19/17918-7)