Development of amperometric and impedimetric sensors based on double hydroxides of nickel and vanadium (alpha-NixV1-x(OH)2) and their nanocomposites with expandable graphite/graphene

• Grant number: 18/16896-7
• Support Opportunities: Scholarships in Brazil - Post-Doctorate
• Effective date (Start): May 01, 2019
• Effective date (End): May 06, 2023
• Field of knowledge: Physical Sciences and Mathematics - Chemistry - Analytical Chemistry
• Principal Investigator: Lucio Angnes
• Grantee: Josué Martins Gonçalves
• Host Institution: Instituto de Química (IQ). Universidade de São Paulo (USP). São Paulo , SP, Brazil
• Associated scholarship(s): 20/06176-7 - Studying the layered hydroxide electrode materials with in situ transmission electron microscopy, BE.EP.PD

Abstract

This postdoctoral project proposes the development of amperometric sensors based on nanostructured alpha-NixV1-x(OH)2 sols synthesized in different proportions of nickel and vanadium from sol-gel method. Such sensors should be obtained in the form of thin films, as well as associated with carbon paste, aiming at the determination and quantification of species of interest such as carbohydrates and diuretic drugs prohibited by the International Olympic Committee (IOC) because they are considered masking agents, such as indapamide, metolazone, thiazides such as chlorothiazide and hydrochlorothiazide. Expanded graphite and reduced graphene oxide (GrEx and rGO, respectively) will be incorporated into the material, thus seeking an increase of the sensor conductivity, in addition to stabilizing the alpha phase of the hydroxides formed. The preparation of the solids directly in the presence of expandable graphite or reduced graphene oxide may favor the obtaining of more uniform materials and this possibility should also be tested.From the thermal decomposition of alpha-NixV1-x(OH)2, mixed oxides of nickel/vanadium will be obtained, so amperometric and impedimetric sensors in the form of carbon paste electrodes will be developed containing GrEx and rGO, for the determination and quantification of species of interest. The study of these new amperometric and impedimetric sensors should be performed using different electrochemical techniques (cyclic voltammetry, electrochemical impedance spectroscopy and pulse techniques).The sensors developed in this project should be used in conjunction with flow electroanalytical techniques such as Flow Injection Analysis (FIA) and Batch Injection Analysis (BIA). For such applications, electrochemical cells should be build and optimized for the subsequent application of these sensors. The use of these techniques in flow will allow the development of methodologies for the determination and quantification of the species of interest, which can be oxidized (or reduced) by the sensors developed in this project.

Scientific publications

(23)

(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)

ROSSINI, PAMELA DE O.; LAZA, ANABEL; AZEREDO, NATHALIA F. B.; GONCALVES, JOSUE M.; FELIX, FABIANA S.; ARAKI, KOITI; ANGNES, LUCIO. Ni-based double hydroxides as electrocatalysts in chemical sensors: A review. TRAC-TRENDS IN ANALYTICAL CHEMISTRY, v. 126, MAY 2020. (18/21489-1, 14/50867-3, 17/13137-5, 18/16896-7)

AZEREDO, NATHALIA F. B.; GONCALVES, JOSUE M.; ROSSINI, PAMELA O.; ARAKI, KOITI; WANG, JOSEPH; ANGNES, LUCIO. Uric acid electrochemical sensing in biofluids based on Ni/Zn hydroxide nanocatalyst. Microchimica Acta, v. 187, n. 7, JUN 9 2020. (14/50867-3, 17/13137-5, 18/21489-1, 18/16896-7)

GONCALVES, JOSUE M.; MARTINS, PAULO R.; ANGNES, LUCIO; ARAKI, KOITI. Recent advances in ternary layered double hydroxide electrocatalysts for the oxygen evolution reaction. NEW JOURNAL OF CHEMISTRY, v. 44, n. 24, p. 9981-9997, JUN 28 2020. (13/24725-4, 18/21489-1, 18/16896-7)

GONCALVES, JOSUE M.; MATIAS, TIAGO A.; ANGNES, LUCIO; MARTINS, PAULO R.; ARAKI, KOITI. Review-Tetraruthenated Porphyrins and Composites as Catalysts and Sensor Materials: A Short Review. ECS JOURNAL OF SOLID STATE SCIENCE AND TECHNOLOGY, v. 9, n. 6, JAN 8 2020. (13/24725-4, 18/16896-7, 17/13137-5, 18/21489-1, 17/50129-0, 14/50867-3)

GONCALVES, JOSUE M.; DA SILVA, MATHEUS IRENO; ANGNES, LUCIO; ARAKI, KOITI. Vanadium-containing electro and photocatalysts for the oxygen evolution reaction: a review. JOURNAL OF MATERIALS CHEMISTRY A, v. 8, n. 5, p. 2171-2206, FEB 7 2020. (18/21489-1, 18/16896-7)

GONCALVES, JOSUE M.; MARTINS, PAULO R.; ARAKI, KOITI; ANGNES, LUCIO. Recent progress in water splitting and hybrid supercapacitors based on nickel-vanadium layered double hydroxides. JOURNAL OF ENERGY CHEMISTRY, v. 57, p. 496-515, JUN 2021. (13/24725-4, 18/21489-1, 18/16896-7)

GARCIA-OSORIO, DANIEL; HIDALGO-FALLA, PILAR; PERES, HENRIQUE E. M.; GONCALVES, JOSUE M.; ARAKI, KOITI; GARCIA-SEGURA, SERGI; PICASSO, GINO. Silver Enhances Hematite Nanoparticles Based Ethanol Sensor Response and Selectivity at Room Temperature. SENSORS, v. 21, n. 2, JAN 2021. (13/24725-4, 18/16896-7)

GONCALVES, JOSUE M.; IGLESIAS, BERNARDO A.; MARTINS, PAULO R.; ANGNES, LUCIO. Recent advances in electroanalytical drug detection by porphyrin/phthalocyanine macrocycles: developments and future perspectives. ANALYST, v. 146, n. 2, p. 365-381, JAN 21 2021. (18/16896-7, 17/13137-5, 14/50867-3)

SILVA, GUSTAVO THALMER M.; SILVA, KAREN MAGNO; SILVA, CASSIO P.; GONCALVES, JOSUE M.; QUINA, FRANK H.. Hybrid Pigments from Anthocyanin Analogues and Synthetic Clay Minerals. ACS OMEGA, v. 5, n. 41, p. 26592-26600, OCT 20 2020. (18/16896-7)

GONCALVES, JOSUE M.; ROCHA, DIEGO P.; SILVA, MURILLO N. T.; MARTINS, PAULO R.; NOSSOL, EDSON; ANGNES, LUCIO; ROUT, CHANDRA SEKHAR; MUNOZ, RODRIGO A. A.. Feasible strategies to promote the sensing performances of spinel MCo2O4 (M = Ni, Fe, Mn, Cu and Zn) based electrochemical sensors: a review. JOURNAL OF MATERIALS CHEMISTRY C, v. 9, n. 25, p. 7852-7887, JUL 7 2021. (17/13137-5, 18/16896-7, 14/50867-3, 20/00325-0)

RUIZ-MONTOYA, JOSE G.; QUISPE-GARRIDO, LADY V.; CALDERON GOMEZ, J. C.; BAENA-MONCADA, ANGELICA M.; GONCALVES, JOSUE M.. Recent progress in and prospects for supercapacitor materials based on metal oxide or hydroxide/biomass-derived carbon composites. SUSTAINABLE ENERGY & FUELS, v. 5, n. 21, SEP 2021. (18/16896-7)

GONCALVES, JOSUE M.; KUMAR, ABHISHEK; DA SILVA, MATHEUS I.; TOMA, HENRIQUE E.; MARTINS, PAULO R.; ARAKI, KOITI; BERTOTTI, MAURO; ANGNES, LUCIO. Nanoporous Gold-Based Materials for Electrochemical Energy Storage and Conversion. ENERGY TECHNOLOGY, v. 9, n. 5, MAR 2021. (18/16896-7, 17/13137-5, 18/21489-1)

GONCALVES, JOSUE M.; DA SILVA, MATHEUS I.; HASHEMINEJAD, MEISAM; TOMA, HENRIQUE E.; ARAKI, KOITI; MARTINS, PAULO R.; ANGNES, LUCIO. Recent Progress in Core@Shell Sulfide Electrode Materials for Advanced Supercapacitor Devices. BATTERIES & SUPERCAPS, MAR 2021. (13/24725-4, 18/21489-1, 18/16896-7, 14/50867-3, 17/13137-5)

REGIART, MATIAS; KUMAR, ABHISHEK; GONCALVES, JOSUE M.; SILVA JUNIOR, GILBERTO J.; MASINI, JORGE CESAR; ANGNES, LUCIO; BERTOTTI, MAURO. An Electrochemically Synthesized Nanoporous Copper Microsensor for Highly Sensitive and Selective Determination of Glyphosate. CHEMELECTROCHEM, v. 7, n. 7, p. 1558-1566, APR 1 2020. (18/16896-7, 19/14418-3, 18/08782-1, 19/06293-6)

GONCALVES, JOSUE M.; DA SILVA, MATHEUS I.; HASHEMINEJAD, MEISAM; TOMA, HENRIQUE E.; ARAKI, KOITI; MARTINS, PAULO R.; ANGNES, LUCIO. Recent Progress in Core@Shell Sulfide Electrode Materials for Advanced Supercapacitor Devices. BATTERIES & SUPERCAPS, v. 4, n. 9, p. 1397-1427, SEP 2021. (18/21489-1, 18/16896-7, 14/50867-3, 13/24725-4, 17/13137-5)

DA SILVA, I, MATHEUS; MACHADO, ITALO R.; TOMA, HENRIQUE E.; ARAKI, KOITI; ANGNES, LUCIO; GONCALVES, JOSUE M.. Recent progress in water-splitting and supercapacitor electrode materials based on MOF-derived sulfides. JOURNAL OF MATERIALS CHEMISTRY A, v. 10, n. 2, NOV 2021. (13/24725-4, 18/21489-1, 18/16896-7)

GONCALVES, JOSUE M.; MARTINS, PAULO R.; ROCHA, DIEGO P.; MATIAS, TIAGO A.; JULIAO, MURILO S. S.; MUNOZ, RODRIGO A. A.; ANGNES, LUCIO. Recent trends and perspectives in electrochemical sensors based on MOF-derived materials. JOURNAL OF MATERIALS CHEMISTRY C, v. 9, n. 28, p. 8718-8745, JUL 28 2021. (14/50867-3, 17/13137-5, 18/16896-7, 20/00325-0)

GONCALVES, JOSUE M.; LIMA, IRLAN S.; AZEREDO, NATHALIA F. B.; ROCHA, DIEGO P.; DE SIERVO, ABNER; ANGNES, LUCIO. iVCe-Layered Double Hydroxide as Multifunctional Nanomaterials for Energy and Sensor Application. FRONTIERS IN MATERIALS, v. 8, NOV 29 2021. (17/13137-5, 20/00325-0, 07/08244-5, 07/54829-5, 18/16896-7, 14/50867-3)

SANTOS, BERLANE G.; GONCALVES, JOSUE M.; ROCHA, DIEGO P.; HIGINO, GIANE S.; YADAV, THAKUR P.; PEDROTTI, JAIRO J.; AJAYAN, PULICKEL M.; ANGNES, LUCIO. Electrochemical sensor for isoniazid detection by using a WS2/CNTs nanocomposite. SENSORS AND ACTUATORS REPORTS, v. 4, NOV 2022. (19/22126-2, 12/50259-8, 18/16896-7, 17/13137-5, 14/50867-3, 20/00325-0)

GONCALVES, JOSUE M.; SILVA, MURILLO N. T.; NAIK, KUSHA KUMAR; MARTINS, PAULO R.; ROCHA, DIEGO P.; NOSSOL, EDSON; MUNOZ, RODRIGO A. A.; ANGNES, LUCIO; ROUT, CHANDRA SEKHAR. Multifunctional spinel MnCo2O4 based materials for energy storage and conversion: a review on emerging trends, recent developments and future perspectives. JOURNAL OF MATERIALS CHEMISTRY A, v. 9, n. 6, p. 3095-3124, FEB 14 2021. (14/50867-3, 20/00325-0, 18/16896-7, 17/13137-5)

GONCALVES, JOSUE M.; DA SILVA, MATHEUS L.; TOMA, HENRIQUE E.; ANGNES, LUCIO; MARTINS, PAULO R.; ARAKI, KOITI. Trimetallic oxides/hydroxides as hybrid supercapacitor electrode materials: a review. JOURNAL OF MATERIALS CHEMISTRY A, v. 8, n. 21, p. 10534-10570, JUN 7 2020. (18/21489-1, 17/13137-5, 18/16896-7)

SILVA JUNIOR, GILBERTO J.; GUIMARAES SELVA, JESSICA SOARES; SUKERI, ANANDHAKUMAR; GONCALVES, JOSUE M.; REGIART, MATIAS; BERTOTTI, MAURO. Fabrication of dendritic nanoporous gold via a two-step amperometric approach: Application for electrochemical detection of methyl parathion in river water samples. Talanta, v. 226, MAY 2021. (19/14418-3, 18/16896-7, 18/08782-1, 19/06293-6)

ROCHA, DIEGO P.; ATAIDE, VANESSA N.; DE SIERVO, ABNER; GONSALVES, JOSUE M.; MUNOZ, RODRIGO A. A.; PAIXA, THIAGO R. L. C.; ANGNES, LUCIO. Reagentless and sub-minute laser-scribing treatment to produce enhanced disposable electrochemical sensors via additive manufacture. CHEMICAL ENGINEERING JOURNAL, v. 425, DEC 1 2021. (07/08244-5, 18/14462-0, 07/54829-5, 18/16896-7, 14/50867-3, 18/08782-1, 20/00325-0)