Chemical modification of Brazilian vegetable oils from macaw and baru nuts to find new monomers and polymers using maleinization, epoxidation, and carbonation syntheses

• Grant number: 19/11493-4
• Support Opportunities: Scholarships abroad - Research Internship - Doctorate
• Start date: January 15, 2020
• End date: May 16, 2020
• Field of knowledge: Engineering - Materials and Metallurgical Engineering - Nonmetallic Materials
• Principal Investigator: Gilbert Bannach
• Grantee: Rafael Turra Alarcon
• Supervisor: Michael North
• Host Institution: Faculdade de Ciências (FC). Universidade Estadual Paulista (UNESP). Campus de Bauru. Bauru , SP, Brazil
• Institution abroad: University of York, England
• Associated to the scholarship: 18/03460-6 - Structural modification of triglycerides aiming new monomers and polymers, using different synthetic routes: microwave irradiation and photopolymerization, BP.DR

Abstract

This project aims to synthesize and characterize new monomers and polymers using Brazilian vegetable oil from macaw and baru nuts. These vegetable oils will be chemically modified by maleinization, epoxidation, and carbonation reactions. The emphasis is to provide value for bio-commodities, by modifying them into new materials, always following the Green Chemistry Principles. The work consists of three parts. The first is the reaction of vegetable oil and maleic anhydride (maleinization reaction). The second part is the epoxidation of the vegetable oil and then carbonation reaction using CO2. Finally, these modified vegetable oils will be reacted to form new polymers. Simultaneous Thermogravimetric/Derivative Thermogravimetry-Differential Thermal Analysis (TG/DTG-DTA), Differential Scanning Calorimetry (DSC), Mid-Infrared Spectroscopy (MIR), Nuclear Magnetic Resonance (1H-NMR) will be used to characterize all the monomers and polymers. (AU)

Scientific publications

(4)

(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)

ALARCON, RAFAEL T.; LAMB, KATIE J.; CAVALHEIRO, EDER T. G.; NORTH, MICHAEL; BANNACH, GILBERT. A screening process for carbonation of vegetable oils using an aluminum(salen) complex with a further application as weldable polymers. Journal of Applied Polymer Science, v. N/A, p. 14-pg., 2023-04-19. (19/11493-4, 21/14879-0, 21/02152-9)

ALARCON, RAFAEL T.; LAMB, KATIE J.; BANNACH, GILBERT; NORTH, MICHAEL. Opportunities for the Use of Brazilian Biomass to Produce Renewable Chemicals and Materials. CHEMSUSCHEM, v. 14, n. 1, p. 169-188, JAN 7 2021. (18/03460-6, 17/08820-8, 19/11493-4)

ALARCON, RAFAEL T.; GAGLIERI, CAROLINE; LAMB, KATIE J.; NORTH, MICHAEL; BANNACH, GILBERT. Spectroscopic characterization and thermal behavior of baru nut and macaw palm vegetable oils and their epoxidized derivatives. INDUSTRIAL CROPS AND PRODUCTS, v. 154, OCT 15 2020. (17/08820-8, 19/11493-4)

BENITES, ANA BEATRIZ; ALARCON, RAFAEL T.; GAGLIERI, CAROLINE; LAMB, KATIE J.; BANNACH, GILBERT. Effect of metal oxide fillers in urethane dimethacrylate polymer with glycerol obtained by photopolymerization synthesis. JOURNAL OF POLYMER RESEARCH, v. 27, n. 10, p. 11-pg., 2020-09-28. (17/08820-8, 18/03460-6, 19/11493-4)