Development of nanocomposite coatings based on polyurethane modified with exholled argilominerals for application in the control of slow release of soluble fertilizers

• Grant number: 19/18036-8
• Support Opportunities: Scholarships in Brazil - Scientific Initiation
• Start date: November 01, 2019
• End date: December 31, 2021
• Field of knowledge: Physical Sciences and Mathematics - Chemistry - Analytical Chemistry
• Principal Investigator: Cauê Ribeiro de Oliveira
• Grantee: Marcela Pfeifer
• Host Institution: Embrapa Instrumentação Agropecuária. Empresa Brasileira de Pesquisa Agropecuária (EMBRAPA). Ministério da Agricultura, Pecuária e Abastecimento (Brasil). São Carlos , SP, Brazil

Abstract

Despite the indispensable use of agricultural fertilizers to achieve current levels of productivity, chemical nutrients have their effectiveness limited by problems such as ammonia (NH3) volatilization, leaching and / or soil immobilization. One strategy to minimize these problems is to protect the fertilizer with nutrient release barrier materials. Thus, it is desirable that the formed polymer should have a homogeneous adhesive line on the granule surface and be able to control the diffusion of soluble nutrients through its structure, allowing the barrier to assume an active role and not just that of a physical obstacle, which release would occur by mechanical compromise (fracture) of the polymer. The permeation through a polymer can be significantly reduced by the presence of internal diffusional barriers such as finely dispersed nanoclays (in the nanocomposites form). This strategy, although investigated for packaging materials (mainly to reduce gas permeation) has been neglected for fertilizer coating films as well as it has great potential to provide low permeation materials for this application. Thus, this project intends to develop strategies for the dispersion of lamellar nanoclays (mainly montmorillonite) as modifiers of a castor oil-based polymer matrix to control the release of commercial fertilizers such as urea and monoammonium phosphate (MAP). The coated granules will be evaluated to determine the best coating parameters, coating stability, deposition interface and total release time in water immersion and soil incubation assays. The coated materials will be analyzed by Scanning Electron Microscopy (SEM), Infrared Spectrophotometry (FTIR), among other techniques. This proposal will be conducted at Embrapa Instrumentation, focusing on sustainable alternatives for the widespread use of protective coatings in fertilizers

Scientific publications

(4)

(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)

PFEIFER, MARCELA; ANDRADE, FLAVIO A. C.; BORTOLETTO-SANTOS, RICARDO; AOUADA, FAUZE A.; RIBEIRO, CAUE. Effect of Different Surface-Charged Lamellar Materials on Swelling Properties of Nanocomposite Hydrogels. JOURNAL OF POLYMERS AND THE ENVIRONMENT, MAR 2021. (13/03643-0, 20/03259-9, 13/07296-2, 16/10636-8, 19/18036-8)

PFEIFER, MARCELA; ANDRADE, FLAVIO A. C.; BORTOLETTO-SANTOS, RICARDO; AOUADA, FAUZE A.; RIBEIRO, CAUE. Effect of Different Surface-Charged Lamellar Materials on Swelling Properties of Nanocomposite Hydrogels. JOURNAL OF POLYMERS AND THE ENVIRONMENT, v. 29, n. 10, p. 3311-3323, OCT 2021. (19/18036-8, 16/10636-8, 20/03259-9, 13/07296-2, 13/03643-0)

MAJARON, VINICIUS F.; DA SILVA, MARISA G.; PFEIFER, MARCELA; BORTOLETTO-SANTOS, RICARDO; VELLOSO, CAMILA C. V.; KLAIC, RODRIGO; POLITO, WAGNER L.; RIBEIRO, SIDNEY J. L.; BERNARDI, ALBERTO C. C.; FARINAS, CRISTIANE S.; et al. Interaction of Aspergillus niger in Double-Coated Urea Granules Reduces Greenhouse Gas Emissions from N Fertilization. JOURNAL OF SOIL SCIENCE AND PLANT NUTRITION, v. 23, n. 3, p. 10-pg., 2023-05-25. (18/10448-2, 17/18673-2, 20/03259-9, 19/18036-8, 16/10636-8)

PFEIFER, MARCELA; BORTOLETTO-SANTOS, RICARDO; ANDRADE, FLAVIO A. C.; RIBEIRO, SIDNEY J. L.; AOUADA, FAUZE A.; RIBEIRO, CAUE. Hydrotalcite loading boosts the potentially toxic element's retention in hydrogel nanocomposites for environmental treatment. APPLIED CLAY SCIENCE, v. 240, p. 9-pg., 2023-05-11. (19/18036-8, 20/03259-9)