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Awaxs study of homogeneous nucleation on BaO-2SiO2 and Ba2TiOSi2O7

Grant number: 98/05016-0
Support Opportunities:Scholarships abroad - Research
Start date: July 12, 1998
End date: July 24, 1998
Field of knowledge:Engineering - Materials and Metallurgical Engineering - Nonmetallic Materials
Principal Investigator:Valmor Roberto Mastelaro
Grantee:Valmor Roberto Mastelaro
Host Investigator: Olivier Lyon
Host Institution: Pessoa Física
Institution abroad: Laboratoire pour l'Utilisation du Rayonnement Electromagnétique (LURE), France  

Abstract

The objective of this work was to confirm or to refuse a possible relationship between the local structure (first coordination shell around the modifier cations) and the crystal nucleation mechanism in silicate glasses. The EXAFS analysis has shown that glasses that nucleate homogeneously present similar neighborhoods to their isochemical crystalline phases; whereas glasses that nucleate heterogeneously do not. Moreover, materials crystallized in laboratory conditions present different medium I range structure from (nominally) the same crystalline natural mineral phase. (AU)

News published in Agência FAPESP Newsletter about the scholarship:
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VEICULO: TITULO (DATA)
VEICULO: TITULO (DATA)