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| Author(s): |
Marilia Emura
Total Authors: 1
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| Document type: | Doctoral Thesis |
| Press: | São Paulo. |
| Institution: | Universidade de São Paulo (USP). Instituto de Física (IF/SBI) |
| Defense date: | 1999-08-24 |
| Examining board members: |
Frank Patrick Missell;
Renato de Figueiredo Jardim;
Marcelo Knobel;
Hercilio Rodolfo Rechenberg;
Daniel Rodrigues
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| Advisor: | Frank Patrick Missell |
| Abstract | |
Permanent magnets composed of magnetic powders bonded with a polymer represent the fastest growing sector of the magnetic materials market since they are ideal for the fabrication of small motors. This work presents a magnetic and structural characterization of TIve eommereial bonded magnets, Reversible and irreversible components of the total magnetization as well as magnetic interactions in the five commereial magnets are also studied, the magnets are composed by ferrite and MQP-Q nanoerystelline powders and mixtures of these two powders with 80%, 60% and 40% ferrite. Magnelie interactions were analyzed by Henkel plots, gM plots and switching field distributions. In bonded magnets, since the magnetic particles are separated from each other by a binder, it is expected that interactions are mainly dipolar in Nature. There is a progressive change in the data as the fraction of MQP-Q powder is increased. The sample with 100% ferrite shows strong magnetizing interactions at low fields. Date for hybrid magnets present increasing demagnetizing interactions as the fermion of MQP-Q increases and for the 100% MQP-Q sample, the data indicate demagnetizing effects. Reversible and irreversible magnetization components were obtained by applying two methods commanly used in magnetic materials characterization, the DCD -IRM method and the reversible susceptibility method. For the 100% ferrite magnet, in which the reversible component is small, the methods lead lo similar results. The results for both methods diverge as the reversible component! Increases, which in this case occurs with the increase of the MQP-Q powder fraction. The divergence is attributed to the idealized conditions of non-inleracting particles assumed by the DCD-IRM method. Magnetic interactions and lotai magnetization components were also studied in a melt-spun nanocrystalline Nd9Fe85B5 sample. This composition is similar to that of the MQP-Q powder and the magnetic behavior of both the bonded magnetic and the nanocrystalline precursor could be compared. Micromagnetic simulations allowed the evaluation of exchange, anisotropy and magnetostatic interactions on the magnetization reversal of nanocryslalline romposlle systems. The Monte Carlo method was applied lo a linear array of 300 magnetic moments distributed in three grains, two magnetically hard with a soft grain between them. (AU) | |