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(Reference retrieved automatically from Web of Science through information on FAPESP grant and its corresponding number as mentioned in the publication by the authors.)

Synthesis of Low-Density, Carbon-Doped, Porous Hexagonal Boron Nitride Solids

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Author(s):
Gautam, Chandkiram [1, 2] ; Tiwary, Chandra Sekhar [1] ; Lose, Sujin [1, 3] ; Brunetto, Gustavo [4, 1] ; Ozden, Sehmus [1] ; Vinod, Soumya [1] ; Raghavan, Prasanth [1] ; Biradar, Santoshkumar [1] ; Galvao, Douglas Soares [4] ; Ajayan, Pulickel M. [1]
Total Authors: 10
Affiliation:
[1] Rice Univ, Dept Mat Sci & Nano Engn, Houston, TX 7005 - USA
[2] Univ Lucknow, Dept Phys, Lucknow 226007, Uttar Pradesh - India
[3] Madurai Kamaraj Univ, Sch Phys, Madurai 625021, Tamil Nadu - India
[4] Univ Estadual Campinas, Dept Appl Phys, BR-13083959 Campinas, SP - Brazil
Total Affiliations: 4
Document type: Journal article
Source: ACS NANO; v. 9, n. 12, p. 12088-12095, DEC 2015.
Web of Science Citations: 31
Abstract

Here, we report the scalable synthesis and characterization of low-density, porous, three-dimensional (3D) solids consisting of two-dimensional (2D) hexagonal boron nitride (h-BN) sheets. The structures are synthesized using bottom-up, low-temperature (similar to 300 degrees C), solid-state reaction of melamine and boric acid giving rise to porous and mechanically stable interconnected h-BN layers. A layered 3D structure forms due to the formation of h-BN, and significant improvements in the mechanical properties were observed over a range of temperatures, compared to graphene oxide or reduced graphene oxide foams. A theoretical model based on Density Functional Theory (DFT) is proposed for the formation of h-BN architectures. The material shows excellent, recyclable absorption capacity for oils and organic solvents. (AU)

FAPESP's process: 13/08293-7 - CCES - Center for Computational Engineering and Sciences
Grantee:Munir Salomao Skaf
Support type: Research Grants - Research, Innovation and Dissemination Centers - RIDC