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(Reference retrieved automatically from Web of Science through information on FAPESP grant and its corresponding number as mentioned in the publication by the authors.)

Porphyrins as Catalysts in Scalable Organic Reactions

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Author(s):
Barona-Castano, Juan C. [1] ; Carmona-Vargas, Christian C. [1] ; Brocksom, Timothy J. [1] ; de Oliveira, Kleber T. [1]
Total Authors: 4
Affiliation:
[1] Univ Fed Sao Carlos, Dept Quim, BR-13565905 Sao Carlos, SP - Brazil
Total Affiliations: 1
Document type: Review article
Source: Molecules; v. 21, n. 3 MAR 2016.
Web of Science Citations: 56
Abstract

Catalysis is a topic of continuous interest since it was discovered in chemistry centuries ago. Aiming at the advance of reactions for efficient processes, a number of approaches have been developed over the last 180 years, and more recently, porphyrins occupy an important role in this field. Porphyrins and metalloporphyrins are fascinating compounds which are involved in a number of synthetic transformations of great interest for industry and academy. The aim of this review is to cover the most recent progress in reactions catalysed by porphyrins in scalable procedures, thus presenting the state of the art in reactions of epoxidation, sulfoxidation, oxidation of alcohols to carbonyl compounds and C-H functionalization. In addition, the use of porphyrins as photocatalysts in continuous flow processes is covered. (AU)

FAPESP's process: 15/21110-4 - Exploiting photocatalyzed reactions under continuous flow conditions by using porphyrinoid systems: (C-FlowPhotoChem)
Grantee:Kleber Thiago de Oliveira
Support type: Regular Research Grants
FAPESP's process: 13/07276-1 - CEPOF - Optics and Photonic Research Center
Grantee:Vanderlei Salvador Bagnato
Support type: Research Grants - Research, Innovation and Dissemination Centers - RIDC
FAPESP's process: 11/13993-2 - Methodologies for the synthesis of bioactive terpenes
Grantee:Timothy John Brocksom
Support type: Regular Research Grants