Effect of diphenyliodonium hexafluorophosphate on the physical and chemical properties of ethanolic solvated resins containing camphorquinone and 1-phenyl-1,2-propanedione sensitizers as initiators

Author(s)

Dressano, Diogo ^[1] ; Palialol, Alan Rodrigo ^[1] ; Xavier, Thaty A. ^[2] ; Braga, Roberto R. ^[2] ; Oxman, Joe D. ^[3] ; Watts, David C. ^[4] ; Marchi, Giselle Maria ^[1] ; Lima, Adriano Fonseca ^[5]

Affiliation

^[1] Univ Estadual Campinas, Piracicaba Dent Sch, Dept Restorat Dent, Av Limeira 901, Mail Box 52, BR-13414903 Sao Paulo - Brazil

^[2] Univ Sao Paulo, Sch Dent, Dept Biomat & Oral Biol, Av Prof Lineu Prestes 2227, BR-05508000 Sao Paulo, SP - Brazil

^[3] 3M Co, ESPE Dent Prod Div 3M, 260-2A-10 3M Ctr, St Paul, MN 55144 - USA

^[4] Univ Manchester, Sch Dent, Manchester M13 9PL, Lancs - England

^[5] Univ Paulista, Dent Res Div, Rua Doutor Bacelar 1212, BR-04026002 Sao Paulo - Brazil

• Document type: Journal article
• Source: Dental Materials; v. 32, n. 6, p. 756-764, JUN 2016.
• Web of Science Citations: 3

Abstract

Objectives. To evaluate the effects of the diphenyliodonium hexafluorophosphate (DPI) on the physical and mechanical properties of solvated dental adhesive resins containing camphorquinone (CQ) and/or 1-phenyl-1,2-propanedione (PPD) as initiators. Methods. Model solvated resins containing bisphenol glycidyl methacrylate (BisGMA); triethyleneglycol dimethacrylate (TEGDMA); 1,3-glycerol dimethacrylate (GDMA); 2-hydroxyethyl methacrylate (HEMA); dimethylaminoethyl amine benzoate (EDAB) and ethanol were prepared. The resins were divided in 24 test groups according to the incorporated initiator systems (CQ-0.5 or 1 mol%; PPD-0.5 or 1 mol%; CQ+ PPD-0.5 or 1 mol%) as well the presence of DPI (0, 0.5 or 1 mol%). Degree of conversion (using Fourier-transformed near infra-red spectroscopy), flexural strength and modulus by three point bending, cohesive strength and water sorption and solubility were measured. Data were statistically analyzed by one and two way ANOVA and Tukey's test (alpha = 0.05). Results. DPI increased the degree of conversion of all materials tested. Camphorquinone promoted higher degree of conversion than resins containing only PPD or CQ+ PPD. Generally, the resins containing PPD + CQ with DPI presented higher flexural strength and modulus, cohesive strength, as well lower water sorption and solubility. Significance. The use of PPD combined with CQ can increase the physical properties of the solvated resins. DPI improved the monomer conversion of all experimental materials and can positively modulate most of the physical properties of the solvated resins. (C) 2016 Academy of Dental Materials. Published by Elsevier Ltd. All rights reserved. (AU)

• FAPESP's process: 13/09989-5 - Influence of different photo-initiators and polymerization accelerators in the chemical and mechanical properties of experimental adhesive systems
• Grantee: Diogo Dressano
• Support Opportunities: Scholarships in Brazil - Master