A catalyst layer optimisation approach using electrochemical impedance spectroscopy for PEM fuel cells operated with pyrolysed transition metal-N-C catalysts

Author(s)

Malko, Daniel ^[1] ; Lopes, Thiago ^[2] ; Ticianelli, Edson A. ^[2] ; Kucernak, Anthony ^[1]

Affiliation

^[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, South Kensington Campus, London SW7 2AZ - England

^[2] Inst Quim Sao Carlos, BR-13566590 Sao Carlos, SP - Brazil

• Document type: Journal article
• Source: Journal of Power Sources; v. 323, p. 189-200, AUG 15 2016.
• Web of Science Citations: 12

Abstract

The effect of the ionomer to carbon (I/C) ratio on the performance of single cell polymer electrolyte fuel cells is investigated for three different types of non-precious metal cathodic catalysts. Polarisation curves as well as impedance spectra are recorded at different potentials in the presence of argon or oxygen at the cathode and hydrogen at the anode. It is found that a optimised ionomer content is a key factor for improving the performance of the catalyst. Non-optimal ionomer loading can be assessed by two different factors from the impedance spectra. Hence this observation could be used as a diagnostic element to determine the ideal ionomer content and distribution in newly developed catalyst-electrodes. An electrode morphology based on the presence of inhomogeneous resistance distribution within the porous structure is suggested to explain the observed phenomena. The back-pressure and relative humidity effect on this feature is also investigated and supports the above hypothesis. We give a simple flowchart to aid optimisation of electrodes with the minimum number of trials. (C) 2016 The Authors. Published by Elsevier B.V. (AU)

• FAPESP's process: 13/16930-7 - Electrocatalysis V: electrocatalytic processes of chemical and electrical energy interconversion
• Grantee: Edson Antonio Ticianelli
• Support Opportunities: Research Projects - Thematic Grants