Study of sugar cane bagasse fly ash as electrode material for capacitive deionization

Author(s)

Lado, Julio J. ; Zornitta, Rafael L. ; Calvi, Felipe A. ; Tejedor-Tejedor, M. Isabel ; Anderson, Marc A. ; Ruotolo, Luis A. M.

• Document type: Journal article
• Source: JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS; v. 120, p. 389-398, JUL 2016.
• Web of Science Citations: 14

Abstract

An abundant low-cost biowaste material such as sugar cane bagasse fly ash (SCBFA) was evaluated in this work as a capacitive deionization (CDI) electrode for brackish water desalination applications. A thermal treatment of SCBFA at different temperatures (200-800 degrees C) was explored as a way to improve structural and electrochemical properties. Pyrolysis at 200 degrees C resulted in an increase of the surface oxygen groups (SOG) that drastically improved electrode wettability. As a consequence, not only specific capacitance values increased (from 33 to 55 Fg(-1)) but also maximum salt adsorption capacity (mSAC, from 2.9 to 5.3 mg g(-1)). Higher temperatures led to higher specific surface areas materials but also to the decomposition of SOG. This resulted in lower mSAC values but still higher than pre-heated SCBFA. Under brackish water concentrations (40 mM NaCl) the observed mSAC values reached 6.2 mg g(-1), showing the potential of the T200 material as CDI electrode. (C) 2016 Elsevier B.V. All rights reserved. (AU)

• FAPESP's process: 15/16107-4 - Desalination by capacitive deionization: development of new electrodes and process optimization
• Grantee: Luis Augusto Martins Ruotolo
• Support Opportunities: Regular Research Grants