New strategies for synthesis and immobilization of methalophtalocyanines onto kaolinite: Preparation, characterization and chemical stability evaluation

Author(s)

da Silva, Tiago Honorato ; de Souza, Thalita F. M. ; Ribeiro, Anderson Orzari ; Calefi, Paulo Sergio ; Ciuffi, Katia Jorge ; Nassar, Eduardo Jose ; Molina, Eduardo Ferreira ; Hamer, Peter ; de Faria, Emerson Henrique

• Document type: Journal article
• Source: DYES AND PIGMENTS; v. 134, p. 41-50, NOV 2016.
• Web of Science Citations: 4

Abstract

This study presents results concerning the one-step synthesis and immobilization of a metal-lophthalocyanine on kaolinite as support/catalyst. X-ray diffractometry (XRD), nuclear magnetic resonance (NMR) and infrared (FTIR), UV/Visible (UV/Vis) and X-ray photoelectron (XPS) spectroscopies, thermal analyses, textural analyses (BET) and scanning electron microscopy (SEM) aided for the characterization of the materials. The FTIR, XPS and UV/Vis absorption spectra confirmed metallophthalocyanine formation. XRD analysis provided data on the structural disorganization of kaolinite during the synthesis of metallophthalocyanine, corroborated by SEM. NMR revealed that partial dissolution of aluminum from the octahedral kaolinite sheets was possible, which should release Al into the medium and, together with phthalonitrile, promote cyclomerization of the phthalocyanine macrocycle. (C) 2016 Elsevier Ltd. All rights reserved. (AU)

• FAPESP's process: 13/19523-3 - Functional Biohybrid materials based on layered and/or fibrous natural clays with multifaceted applications
• Grantee: Emerson Henrique de Faria
• Support Opportunities: Regular Research Grants