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(Reference retrieved automatically from Web of Science through information on FAPESP grant and its corresponding number as mentioned in the publication by the authors.)

A Comparison among Viscosity, Density, Conductivity, and Electrochemical Windows of N-n-Butyl-N-methylpyrrolidinium and Triethyl-n-pentylphosphonium Bis(fluorosulfonyl imide) Ionic Liquids and Their Analogues Containing Bis(trifluoromethylsulfonyl) Imide Anion

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Author(s):
Sanchez-Ramirez, Nedher [1, 2] ; Assresahegn, Birhanu Desalegn [2] ; Belanger, Daniel [2] ; Torresi, Roberto M. [1]
Total Authors: 4
Affiliation:
[1] Univ Sao Paulo, Inst Quim, Dept Quim Fundamental, Av Prof Lineu Prestes 748, BR-05508000 Sao Paulo - Brazil
[2] Univ Quebec Montreal, Dept Chem, Case Postale 8888 Succursale Ctr Ville, Montreal, PQ H3C 3P8 - Canada
Total Affiliations: 2
Document type: Journal article
Source: JOURNAL OF CHEMICAL AND ENGINEERING DATA; v. 62, n. 10, p. 3437-3444, OCT 2017.
Web of Science Citations: 11
Abstract

Ionic liquid consists of an organic cation and generally an inorganic anion. The properties of liquids can be modulated by changing the anion or the cation or both. Two ionic liquids derived from the anion {[}FSI] were synthesized and characterized: (N-n-butyl-N-methylpyrroliclinium bis-(fluorosulfonyl imide), {[}BMPYR] {[}FSI]) and triethyl-n-pentylphosphonium bis (fluorosulfonyl)imide), {[}P-2225] {[}FSI]). We also report the comparison with {[}TFSI] based ionic liquids, namely: (N-n-butyl-N-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide), {[}BMPYR] {[}TFSI]), (N-n-butyl-N-methylpiperidinium bis(trifluoromethylsulfonyl)imide), {[}BMP]{[}TFSI]), triethyl-n-pentylphosphonium bis(trifluoromethylsulfonyl)imide), {[}P-2225] {[}TFSI]), and (triethyl(2-methoxyethyl) phosphonium bis(trifluoromethylsulfonyl imide), {[}P-222201] {[}TFSI]. Thermophysical properties, such as viscosity (298.15-373.15 K), density (298.15-373.15 K), conductivity (298.15-361.15 K), electro-chemical (cutoff density current within 150 mu A.cm(-2)), and thermal stability (303.15-973.15 K) were experimentally determined. The results showed that {[}FSI] derivatives exhibit better transport properties and lower thermal and electrochemical stability when compared with their {[}TFSI] counterparts. (AU)

FAPESP's process: 15/26308-7 - Optimization of the physicochemical properties of nano -structured materials for applications in molecular recognition, catalysis and energy conversion/storage
Grantee:Roberto Manuel Torresi
Support type: Research Projects - Thematic Grants
FAPESP's process: 14/01987-6 - Study of lithium intercalation into different nanostructured cathode based on oxides of transition metal using ionic liquid (ILs) with low viscosity synthesized from phosphonium and tetracyanoborate like electrolytes.
Grantee:Nédher Sánches Ramírez
Support type: Scholarships in Brazil - Post-Doctorate
FAPESP's process: 15/11164-0 - Study of lithiation of silicon nanopowder produced by induced plasma using ionic liquids as electrolytes
Grantee:Nédher Sánches Ramírez
Support type: Scholarships abroad - Research Internship - Post-doctor