| Full text | |
| Author(s): |
Sanchez-Ramirez, Nedher
[1, 2]
;
Assresahegn, Birhanu Desalegn
[2]
;
Belanger, Daniel
[2]
;
Torresi, Roberto M.
[1]
Total Authors: 4
|
| Affiliation: | [1] Univ Sao Paulo, Inst Quim, Dept Quim Fundamental, Av Prof Lineu Prestes 748, BR-05508000 Sao Paulo - Brazil
[2] Univ Quebec Montreal, Dept Chem, Case Postale 8888 Succursale Ctr Ville, Montreal, PQ H3C 3P8 - Canada
Total Affiliations: 2
|
| Document type: | Journal article |
| Source: | JOURNAL OF CHEMICAL AND ENGINEERING DATA; v. 62, n. 10, p. 3437-3444, OCT 2017. |
| Web of Science Citations: | 11 |
| Abstract | |
Ionic liquid consists of an organic cation and generally an inorganic anion. The properties of liquids can be modulated by changing the anion or the cation or both. Two ionic liquids derived from the anion {[}FSI] were synthesized and characterized: (N-n-butyl-N-methylpyrroliclinium bis-(fluorosulfonyl imide), {[}BMPYR] {[}FSI]) and triethyl-n-pentylphosphonium bis (fluorosulfonyl)imide), {[}P-2225] {[}FSI]). We also report the comparison with {[}TFSI] based ionic liquids, namely: (N-n-butyl-N-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide), {[}BMPYR] {[}TFSI]), (N-n-butyl-N-methylpiperidinium bis(trifluoromethylsulfonyl)imide), {[}BMP]{[}TFSI]), triethyl-n-pentylphosphonium bis(trifluoromethylsulfonyl)imide), {[}P-2225] {[}TFSI]), and (triethyl(2-methoxyethyl) phosphonium bis(trifluoromethylsulfonyl imide), {[}P-222201] {[}TFSI]. Thermophysical properties, such as viscosity (298.15-373.15 K), density (298.15-373.15 K), conductivity (298.15-361.15 K), electro-chemical (cutoff density current within 150 mu A.cm(-2)), and thermal stability (303.15-973.15 K) were experimentally determined. The results showed that {[}FSI] derivatives exhibit better transport properties and lower thermal and electrochemical stability when compared with their {[}TFSI] counterparts. (AU) | |
| FAPESP's process: | 15/11164-0 - Study of lithiation of silicon nanopowder produced by induced plasma using ionic liquids as electrolytes |
| Grantee: | Nédher Sánches Ramírez |
| Support Opportunities: | Scholarships abroad - Research Internship - Post-doctor |
| FAPESP's process: | 14/01987-6 - Study of lithium intercalation into different nanostructured cathode based on oxides of transition metal using ionic liquid (ILs) with low viscosity synthesized from phosphonium and tetracyanoborate like electrolytes. |
| Grantee: | Nédher Sánches Ramírez |
| Support Opportunities: | Scholarships in Brazil - Post-Doctoral |
| FAPESP's process: | 15/26308-7 - Optimization of the physicochemical properties of nano -structured materials for applications in molecular recognition, catalysis and energy conversion/storage |
| Grantee: | Roberto Manuel Torresi |
| Support Opportunities: | Research Projects - Thematic Grants |