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(Reference retrieved automatically from Web of Science through information on FAPESP grant and its corresponding number as mentioned in the publication by the authors.)

Flexible conductive poly(styrene-butadiene-styrene)/carbon nanotubes nanocomposites: Self-assembly and broadband electrical behavior

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Author(s):
Ferreira Santos, Joao Paulo [1] ; Franca Melo, Guilherme Henrique [1] ; Goncalves, Andre Marino [2] ; Eiras, Jose Antonio [2] ; Suman Bretas, Rosario Elida [1]
Total Authors: 5
Affiliation:
[1] Univ Fed Sao Carlos, Dept Mat Engn, Rodovia Washington Luis, Km 235, POB 676, BR-13565905 Sao Carlos, SP - Brazil
[2] Univ Fed Sao Carlos, Dept Phys, Ferro Mat Grp, Rodovia Washington Luis, Km 235, POB 676, BR-13565905 Sao Carlos, SP - Brazil
Total Affiliations: 2
Document type: Journal article
Source: Journal of Applied Polymer Science; v. 135, n. 34 SEP 10 2018.
Web of Science Citations: 1
Abstract

Flexible conductive nanocomposites with the ability of self-assembly into well-ordered structures are promising multifunctional materials for energy conversion and storage devices. In this work, flexible nanocomposites based on multi-walled carbon nanotubes (MWCNTs) and poly(styrene-butadiene-styrene) (SBS) were obtained by solution casting, followed by a post-annealing treatment, during 7 days at 110 degrees C, to enable the self-organization of the SBS. The impact of the MWCNTs on the self-assembly was studied by atomic force microscopy and Small angle X-rays scattering, and the conductivity of these nanocomposites was analyzed over the broadband frequency range, that is, 10(-1)-10(6) Hz. The results revealed that the lower MWCNTs loadings (approximate to 0.2 v %) were the most suitable to achieve a conductive network through the SBS, maintaining self-assembled domains. These domains include hexagonally packed cylinders and alternating lamellae. Furthermore, at loadings above 1 v %, the impact of further MWCNTs addition on the conductivity was marginal over the whole frequency range and the self-assembly tendency was progressively reduced. (c) 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018, 135, 46650. (AU)

FAPESP's process: 14/17597-2 - Hybrid nanocomposites based on block copolymers for application in supercapacitors
Grantee:João Paulo Ferreira Santos
Support type: Scholarships in Brazil - Doctorate
FAPESP's process: 13/03118-2 - Visulization, characterization and manipulation of ferroelectric and magnetic domains in multiferroics
Grantee:André Marino Gonçalves
Support type: Scholarships in Brazil - Doctorate
FAPESP's process: 16/03667-4 - Electrospinning of ceramic nanofibers for polymeric nanocomposites
Grantee:Rosario Elida Suman Bretas
Support type: Scholarships abroad - Research
FAPESP's process: 13/07296-2 - CDMF - Center for the Development of Functional Materials
Grantee:Elson Longo da Silva
Support type: Research Grants - Research, Innovation and Dissemination Centers - RIDC