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(Reference retrieved automatically from Web of Science through information on FAPESP grant and its corresponding number as mentioned in the publication by the authors.)

Hydration-Dependent Hierarchical Structures in Block Copolymer-Surfactant Complex Salts

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Author(s):
Ferreira, Guilherme A. [1] ; Piculell, Lennart [2] ; Loh, Watson [1]
Total Authors: 3
Affiliation:
[1] Univ Campinas UNICAMP, Inst Chem, POB 6154, BR-13083970 Campinas, SP - Brazil
[2] Lund Univ, Div Phys Chem, POB 124, S-22100 Lund - Sweden
Total Affiliations: 2
Document type: Journal article
Source: MACROMOLECULES; v. 51, n. 23, p. 9915-9924, DEC 11 2018.
Web of Science Citations: 2
Abstract

Block copolymer-surfactant ``complex salts{''} (BCPCS), containing one neutral water-soluble block and one polyion/surfactant-ion block, were prepared from poly (acrylamide)-block-poly(acrylic acid) block copolymers by neutralizing the acrylate charges with cationic dodecyl- or hexadecyltrimethylammonium surfactant counterions. The BCPCS were studied in hydrated samples containing 20-99 wt % water (and no additional ions) employing small-angle X-ray scattering (SAXS), dynamic light scattering (DLS), and visual inspection. Selected samples in D2O were also investigated. The results reveal for the first time, for hydrated samples, the formation of ordered hierarchical structures on both block copolymer and surfactant length scales, analogous to structures that have previously been reported for solvent-free block copolymer surfactant complexes in the solid or melt. The BCPCS structures do not dissolve but display a finite swelling also in the presence of excess water. The structure on the BCP length scale (lamellar or hexagonal) depends only on the BCP, whereas the structure on the CS length scale (hexagonal or micellar cubic) depends on both the surfactant ion and the water content. The results strongly suggest that the observed concentrated hierarchical structures are the equilibrium states for BCPCS in water, although small aggregates formed reproducibly in the dilute regime have been reported for BCPCS and similar systems, collectively known as complex coacervate core micelles (C3Ms). (AU)

FAPESP's process: 15/25406-5 - Organizing matter: colloids formed by association of surfactants, polymers and nanoparticles
Grantee:Watson Loh
Support Opportunities: Research Projects - Thematic Grants