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(Reference retrieved automatically from Web of Science through information on FAPESP grant and its corresponding number as mentioned in the publication by the authors.)

Calibration strategies for determination of the In content in discarded liquid crystal displays (LCD) from mobile phones using laser-induced breakdown spectroscopy (LIBS)

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Author(s):
Andrade, Daniel Fernandes [1] ; Fortunato, Felipe Manfroi [1] ; Pereira-Filho, Edenir Rodrigues [1]
Total Authors: 3
Affiliation:
[1] Univ Fed Sao Carlos, Dept Chem, Grp Appl Instrumental Anal, BR-13565905 Sao Carlos, SP - Brazil
Total Affiliations: 1
Document type: Journal article
Source: Analytica Chimica Acta; v. 1061, p. 42-49, JUL 11 2019.
Web of Science Citations: 6
Abstract

Mobile phones are one of the fastest growing types of electronic waste disposed of world-wide. One of the main components in these devices is the LCD (liquid crystal display) panel that contains conductive electrodes made of indium tin oxide. A large amount of In, which is categorized as a critical raw element, has been used to manufacture indium tin oxide films. This study applies laser-induced breakdown spectroscopy (LIBS) for the analysis of LCD samples from mobile phones in order to determine the In content. Both conventional univariate calibration and non-traditional calibration using different transition energies (emission lines), named multi-energy calibration (MEC), were assessed. To evaluate the accuracy of the results, Method EPA 3052 was performed for acid digestion of the samples using microwave-assistance, and the In content was determined by ICP OES. Indium concentrations ranged from 35 to 47 mg kg(-1) for all samples evaluated. The results showed the best accuracy for LIBS methods after the spectra were normalized by the carbon line at 193.09 nm. The univariate-LIBS model showed a standard error of calibration (SEC) about 10-fold lower than the samples' concentration, LOD and LOQ of 0.3 and 1.0 mg kg(-1), respectively. MEC proved to be a fast and efficient alternative for direct solid analysis, and In concentrations were determined by LIBS using only two calibration pellets. The LOD and LOQ for MEC-LIBS method were 2.1 and 7 mg kg(-1), respectively. (C) 2019 Elsevier B.V. All rights reserved. (AU)

FAPESP's process: 16/01513-0 - Laser-Induced Breakdown Spectroscopy (LIBS) application in the analyses of electronic waste (printed circuit boards and polymers), food and difficult preparation liquid samples
Grantee:Edenir Rodrigues Pereira Filho
Support type: Regular Research Grants
FAPESP's process: 16/17304-0 - Proposition of methods for direct analysis of electronic waste samples: determination of precious, strategic and toxic elements in printed circuits boards and LCD screens
Grantee:Daniel Fernandes de Andrade
Support type: Scholarships in Brazil - Doctorate