Advanced search
Start date
Betweenand
(Reference retrieved automatically from Web of Science through information on FAPESP grant and its corresponding number as mentioned in the publication by the authors.)

Structural and photoluminescence properties of Eu3+-doped (Y2.99-xGdx)Al5O12 phosphors under vacuum ultraviolet and ultraviolet excitation

Full text
Author(s):
Show less -
Carvalho, Iure da S. [1] ; Barbosa, Amanda I. dos S. [1] ; Silva, Ariosvaldo J. S. [1] ; Nascimento, Patresio A. M. [1] ; Andrade, Adriano B. [1] ; Sampaio, David V. [2] ; Junot, Danilo O. [1] ; da Cunha, Thiago R. [2] ; Jesus, Lilian M. [2] ; Silva, Ronaldo S. [1] ; Rezende, Marcos V. dos S. [1]
Total Authors: 11
Affiliation:
[1] Univ Fed Sergipe, Dept Fis, GNF, BR-49100000 Sao Cristovao, SE - Brazil
[2] Univ Fed Sao Carlos, Dept Fis, BR-13565905 Sao Carlos, SP - Brazil
Total Affiliations: 2
Document type: Journal article
Source: Materials Chemistry and Physics; v. 228, p. 9-14, APR 15 2019.
Web of Science Citations: 0
Abstract

Eu-doped (Y2.99-xGdx)Al5O12 phosphors (with x = 0, 0.5, 1, 1.5, 2, 2.5, and 2.99) were prepared by a sol-gel method using polyvinylalcohol (PVA) as gel agent. The crystal structures were characterized through X-ray diffraction and the resulting data were refined by the Rietveld method, which shows a linear increase of the lattice parameter with the Gd content. Further structural characterization was carried out via Raman spectroscopy. The effect of substituting Y3+ by Gd3+ on the Eu-doped Y3Al5O12 (YAG) photoluminescence properties was investigated using vacuum ultraviolet (VUV) and ultraviolet (UV) excitation. The excitation and emission spectra of the produced (Y2.99-xGdx)Al5O12 phosphors indicate that their luminescence properties are strongly dependent on the Gd3+ substitution. Our results also reveal a nonlinear decrease in the band-gap of these materials by increasing the Gd concentration. (AU)

FAPESP's process: 16/15962-0 - Correlation between materials structure and dynamic and optical properties of (Ax, A'1-x)O + SiO2 (A, A' = Pb, Ni, Co, Fe, Cr) series: Raman scattering and molecular dynamics simulations
Grantee:David Vieira Sampaio
Support Opportunities: Scholarships in Brazil - Post-Doctoral
FAPESP's process: 13/07793-6 - CEPIV - Center for Teaching, Research and Innovation in Glass
Grantee:Edgar Dutra Zanotto
Support Opportunities: Research Grants - Research, Innovation and Dissemination Centers - RIDC