Photocatalytic activity of Nb heterostructure (NaNbO3/Na2Nb4O11) and Nb/clay materials in the degradation of organic compounds

Author(s)

Asencios, Yvan J. O. ^[1] ; Quijo, Marcella V. ^[1] ; Marcos, Francielle C. F. ^{[2, 3]} ; Nogueira, Andre E. ^[4] ; Rocca, Rene R. ^[1] ; Assaf, Elisabete M. ^[2]

Affiliation

^[1] Fed Univ Sao Paulo IMar UNIFESP, Inst Marine Sci, BR-11030100 Santos, SP - Brazil

^[2] Univ Sao Paulo, Sao Carlos Inst Chem, BR-13566590 Sao Carlos, SP - Brazil

^[3] Univ Sao Paulo, Escola Politecn, BR-05508010 Sao Paulo, SP - Brazil

^[4] Univ Fed Ouro Preto, BR-35400000 Ouro Preto, MG - Brazil

• Document type: Journal article
• Source: Solar Energy; v. 194, p. 37-46, DEC 2019.
• Web of Science Citations: 0

Abstract

In this article, Nb heterostructure-based (NaNbO3/Na2Nb4O11) and Nb/Clay-based materials were prepared, characterized and evaluated for the Rhodamine B (C28H31ClN2O3) photodegradation under UV radiation (253.7 nm). As far as this research understands, this is the first time that the photocatalytic activity of the Nb heterostructure (NaNbO3/Na2Nb4O11) is reported. Nb heterostructure is composed of sodium niobate and disodium tetraniobium hendecaoxide (NaNbO3/Na2Nb4O11). The material was synthesized by a simple and economic method via basic precipitation of ammoniacal niobium oxalate (NH4 {[}NbO (C2O4)(2)center dot H2O] XH2O) followed by thermal treatment at 500 degrees C. Nb/Clay-based materials were synthesized from the natural clay suspension (Montmorillonite) precursor. The addition of Nb to the natural clay by the methodology employed in this work modified the band-gap energy and increased the specific surface area of the resultant materials (to almost twice the value of the original specific surface area). Furthermore, this addition also decreased the luminescence and trap centres and potentiated the photocatalytic activity of the Nb/Clay materials. The Nb heterostructure showed higher photocatalytic activity in Rhodamine B photodegradation (recorded up to 95% removal at natural conditions). Similar values were reported to Nb/Clay materials. Despite the natural clay having more luminescence and trap centres than Nb/Clay materials, it recorded very low photocatalytic activity. Nb addition to natural clay increased the photocatalytic activity of the material, which would give other use to clay along with being used as an adsorbent. (AU)

• FAPESP's process: 14/24940-5 - Development of solid-catalysts based on semiconductor oxides for the hydrogen production from water splitting
• Grantee: Yvan Jesus Olortiga Asencios
• Support Opportunities: Regular Research Grants
• FAPESP's process: 17/08293-8 - Project 14: direct synthesis of methanol from CO2
• Grantee: Francielle Candian Firmino Marcos
• Support Opportunities: Scholarships in Brazil - Post-Doctoral