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(Reference retrieved automatically from Web of Science through information on FAPESP grant and its corresponding number as mentioned in the publication by the authors.)

Discriminative detection of volatile organic compounds using an electronic nose based on TiO(2 )hybrid nanostructures

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Author(s):
Conti, Patrick P. [1, 2] ; Andre, Rafaela S. [2] ; Mercante, Luiza A. [2, 3] ; Fugikawa-Santos, Lucas [4] ; Correa, Daniel S. [1, 2]
Total Authors: 5
Affiliation:
[1] Fed Univ Sao Carlos UFSCar, Ctr Exact Sci & Technol, Dept Chem, PPGQ, BR-13565905 Sao Carlos, SP - Brazil
[2] Embrapa Instrumentacao, Nanotechnol Natl Lab Agr LNNA, BR-13560970 Sao Carlos, SP - Brazil
[3] Fed Univ Bahia UFBA, Inst Chem, BR-40170280 Salvador, BA - Brazil
[4] Sao Paulo State Univ UNESP, Inst Geosci & Exact Sci, Rio Claro, SP - Brazil
Total Affiliations: 4
Document type: Journal article
Source: SENSORS AND ACTUATORS B-CHEMICAL; v. 344, OCT 1 2021.
Web of Science Citations: 1
Abstract

Volatile organic compounds (VOCs) are environmental pollutants that pose risks to the human health even at very low concentrations. Therefore, fast and sensitive analytical methods capable to discriminate VOCs are highly demanded. Herein, we have successfully synthetized and characterized TiO2 nanofibers (NF) by electrospinning and TiO2 nanoparticles (NP) by sol-gel method to be employed in an electronic nose (e-nose) for monitoring VOCs. Electrical comparison between TiO2-NF and TiO2-NP indicated that the former presented better electrical response, which can be attributed to the better charge transfer along the nanofiber framework. The TiO2 nanostructures were combined with three different polymers, namely poly(3,4ethylenedioxythiophene):polystyrene sulfonate (PEDOT:PSS), polypyrrole (PPy), and polystyrene sulfonate (PSS), which obtained nanocomposites were deposit by drop casting onto gold interdigitated electrodes and used as sensing units of the e-nose. Electrical impedance spectroscopy measurements were employed to collect the enose electrical resistance data, which were treated by Principal Component Analysis (PCA), revealing the system was able to discriminate the three VOCs. Our results indicate that the e-nose system has potential to be employed as a rapid and simple alternative in the detection of VOCs. (AU)

FAPESP's process: 18/08012-1 - Development of nanostructured sensors based on ceramic materials and conducting polymers aiming the monitoring of volatile organic compounds
Grantee:Patrick Pires Conti
Support Opportunities: Scholarships in Brazil - Master
FAPESP's process: 17/12174-4 - Development of hybrid polymer nanofibers for agricultural applications
Grantee:Daniel Souza Corrêa
Support Opportunities: Regular Research Grants
FAPESP's process: 16/23793-4 - Development of nanostructured sensor aiming the detection of volatile compounds for food quality indicators
Grantee:Rafaela da Silveira Andre
Support Opportunities: Scholarships in Brazil - Post-Doctoral