A new approach on synergistic effect and chemical stability of graphene oxide-magnetic nanocomposite in the heterogeneous Fenton degradation of caffeine

Author(s)

Ramirez-Ubillus, Manuel Alejandro ^[1] ; Costa-Serge, Nayara de Melo ^{[1, 2]} ; Hammer, Peter ^[1] ; Pupo Nogueira, Raquel Fernandes ^{[1, 2]}

Affiliation

^[1] Sao Paulo State Univ UNESP, Inst Chem, BR-14800900 Araraquara, SP - Brazil

^[2] UNESP, Inst Chem, Natl Inst Alternat Technol Detect Toxicol Evaluat, BR-14800900 Araraquara, SP - Brazil

• Document type: Journal article
• Source: Environmental Science and Pollution Research; v. 28, n. 39, p. 55014-55028, OCT 2021.
• Web of Science Citations: 0

Abstract

Two compositions of graphene oxide-magnetite nanocomposites were studied as catalysts in the heterogeneous Fenton process. Transmission electron microscopy and X-ray diffraction revealed that the graphene oxide sheets were covered with nanoparticles of magnetite, with an average crystallite size of 7 nm. Infrared spectroscopy analysis indicated that the phases interacted through covalent Fe-O-C bonds. The composites presented significantly improved catalytic activity, compared to pure magnetite, with a synergistic effect of up to a factor of 17.1 for the Fenton degradation of caffeine, achieving total removal after 90 min. This synergistic effect was a consequence of the interaction between the phases, resulting in improved mass transfer of caffeine to the catalyst surface, adsorption and efficient degradation, with enhanced HO center dot generation. The surface reaction constant increased by up to three orders of magnitude, demonstrating the important role of graphene oxide in the degradation kinetics of the heterogeneous Fenton process. The surface-bonded hydroxyl radicals were responsible for caffeine degradation, achieving 9.4 mu mol L-1. After five degradation cycles, a loss of Fe-O-C bonds and increase in oxygenated groups were associated with a small decrease of caffeine removal efficiency, from 98 to 82%, without significant iron leaching, in the dark, and with low consumption of hydrogen peroxide. (AU)

• FAPESP's process: 18/17517-0 - Layered double hydroxide as catalysts in heterogeneous photo Fenton process for degradation of drugs present in hospital effluent
• Grantee: Nayara de Melo Costa Serge
• Support Opportunities: Scholarships in Brazil - Doctorate
• FAPESP's process: 14/50945-4 - INCT 2014: National Institute for Alternative Technologies of Detection, Toxicological Evaluation and Removal of Micropollutants and Radioactivies
• Grantee: Maria Valnice Boldrin
• Support Opportunities: Research Projects - Thematic Grants