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(Reference retrieved automatically from Web of Science through information on FAPESP grant and its corresponding number as mentioned in the publication by the authors.)

An investigation of photovoltaic devices based onp-typeCu(2)Oandn-type gamma-WO(3)junction through an electrolyte solution containing a redox pair

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Author(s):
Resende, Andressa L. S. [1] ; Costa, Antonio G. R. [1] ; Lima, Aline E. B. [2] ; Costa, Maria J. S. [2] ; Longo, Elson [3] ; Cavalcante, Laecio S. [1] ; Santos, Reginaldo S. [1]
Total Authors: 7
Affiliation:
[1] Univ Estadual Piaui, Dept Chem, PPGQ GERATEC, Joao Cabral 2231, POB 381, BR-64002150 Teresina, Piaui - Brazil
[2] Univ Fed Piaui UFPI, Dept Chem, Teresina, Piaui - Brazil
[3] Univ Fed Sao Carlos, CDMF UFSCAR, Sao Carlos, SP - Brazil
Total Affiliations: 3
Document type: Journal article
Source: INTERNATIONAL JOURNAL OF ENERGY RESEARCH; v. 45, n. 2, p. 2797-2809, FEB 2021.
Web of Science Citations: 0
Abstract

In this article, we report a solar cell prepared withp-type cuprous oxide (Cu2O) andn-type gamma-tungsten oxide (gamma-WO3) films combined by an redox electrolyte in a configuration similar to that used in dye-sensitized solar cells. Cu2O films were prepared by the electrochemical method in three different pH conditions. X-ray diffraction patterns revealed that the Cu2O films presented a crystalline phase with cubic structure after deposition, whereas then-type gamma-WO(3)film was prepared by the drop-casting method. Optical analyses showed that both oxide films absorb visible light. After the photoelectrochemical characterization of the films, solar cells configured like a ``sandwich{''} (Cu2O/electrolyte/gamma-WO3) were assembled and investigated under irradiation of 100 mW cm(-2). The solar cell with I-/I3-redox pair showed better results than that prepared with polysulfide K2S/Sn2-electrolyte. For each solar cell, the investigated parameters were short-circuit current density, open-circuit voltage, fill factor, maximum power, and cell efficiency. The method proposed here can be considered new, promising, and simple for the preparation of solar cells with ap-njunction. (AU)

FAPESP's process: 13/07296-2 - CDMF - Center for the Development of Functional Materials
Grantee:Elson Longo da Silva
Support Opportunities: Research Grants - Research, Innovation and Dissemination Centers - RIDC