| Full text | |
| Author(s): |
Vicente, Vinicius Bocci
[1]
;
Olivieri, Gustavo Vieira
[2]
;
dos Santos, Ronaldo Goncalves
[2]
;
Torres, Ricardo Belchior
[2]
Total Authors: 4
|
| Affiliation: | [1] Ctr Univ FEI, Dept Engn Mecan, Ave Humberto de Alencar Castelo Branco 3972, BR-09850901 Sao Bernardo Do Campo, SP - Brazil
[2] Ctr Univ FEI, Dept Engn Quim, Ave Humberto de Alencar Castelo Branco 3972, BR-09850901 Sao Bernardo Do Campo, SP - Brazil
Total Affiliations: 2
|
| Document type: | Journal article |
| Source: | JOURNAL OF CHEMICAL THERMODYNAMICS; v. 168, MAY 2022. |
| Web of Science Citations: | 0 |
| Abstract | |
Volumetric properties for binary mixtures of (glycerol + methanol, or + ethanol, or + 1-propanol, or + 2-propanol, or + 1-butanol) have been determined as a function of composition using experimental data of density at T = (288.15, 293.15, 298.15, 303.15 and 308.15) K and p = 92.3 kPa. The density measurements have been determined by using a vibrating-tube densimeter. The density values enabled the determination of the thermal expansion coefficient and the excess molar volume. The values of excess molar volume were correlated by a Redlich-Kister polynomial and by the Peng-Robinson-Stryjek-Vera equation of state (PRSV EOS). These values were also used in the estimation of the partial molar volumes, excess partial molar volumes and apparent molar volumes. Three different methods were used to determine the partial molar volumes at infinite dilution. For all studied systems, the values of excess molar volumes were negative over the entire composition range and suggest predominance of chemical and structural effects. (C) 2022 Elsevier Ltd. (AU) | |
| FAPESP's process: | 16/02652-3 - Experimental study and modeling of thermodynamics properties of binary systems containing {dimethyl carbonate (DMC) + alcohols} at high pressure |
| Grantee: | Gustavo Vieira Olivieri |
| Support Opportunities: | Scholarships in Brazil - Master |