Hierarchical chabazites synthesized by combining primary and secondary structure-directing agents

Author(s)

Marins, Natalia Hadler ; Pereira, Elen Maria Feliciano ; Alahakoon, Sandamini H. ; Huang, Yining ; Martins, Leandro

• Document type: Journal article
• Source: Microporous and Mesoporous Materials; v. 346, p. 10-pg., 2022-11-04.

Abstract

Modifying the physical and chemical properties of zeolites by altering the synthesis parameters or using post -synthesis treatments may offer additional properties other than those that make them widely used materials. Remarkably, the chabazite SSZ-13 zeolite possesses a small pore opening that provides access to a large cavity, making the structure suitable for converting methanol to products. Herein, we altered the porosity of SSZ-13 by adding various amounts (2, 4, and 8% in relation to the molar silica content) of dimethyloctadecyl[3-(trime-thoxysilyl)propyl] ammonium (DMOAP) into the reaction mixture. The introduction of DMOAP enabled the formation of the pure chabazite structure without affecting the incorporation of aluminum atoms into the zeolite framework. At the same time, its incorporation led to changes in porosity, increasing the external surface area and creating mesopores without affecting the formation of micropores. Concerning the catalytic conversion of methanol into products at low temperatures (210 degrees C), the additional porosity decreased the methanol to dimethyl ether conversion, indicating that the confinement effect plays an essential role in stabilizing the re-action intermediates. However, at higher temperatures (400 degrees C), the mesopores played an essential role in the methanol to olefins reaction by increasing the catalyst lifetime and the conversion over time due to improved accessibility of methanol to reaction intermediates confined in the micropores. (AU)

• FAPESP's process: 19/12201-7 - Selected zeolite structures as supports for transition metal oxides for selective conversion of methane into value added chemicals
• Grantee: Natália Hadler Marins
• Support Opportunities: Scholarships in Brazil - Post-Doctoral
• FAPESP's process: 18/01258-5 - Novel chemical catalytic and photocatalytic processes for the direct conversion of methane and CO2 to products
• Grantee: José Maria Correa Bueno
• Support Opportunities: Research Projects - Thematic Grants
• FAPESP's process: 20/07265-3 - Synthesis of hierarchical mordenite and chabazite zeolites and their catalytic properties
• Grantee: Natália Hadler Marins
• Support Opportunities: Scholarships abroad - Research Internship - Post-doctor
• FAPESP's process: 19/12486-1 - Multi-User Equipment approved in grant 2018/01258-5: gas chromatograph
• Grantee: Leandro Pierroni Martins
• Support Opportunities: Multi-user Equipment Program