Metallo-stannosilicate heterogeneous catalyst for biodiesel production using edible, non-edible and waste oils as feedstock

Author(s)

da Silva, Danilo Antonio ; Santisteban, Oscar A. N. ; de Vasconcellos, Adriano ; Paula, Alex Silva ; Aranda, Donato A. G. ; Giotto, Marcus Vinicius ; Jaeger, Christian ; Nery, Jose G.

• Document type: Journal article
• Source: JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING; v. 6, n. 4, p. 10-pg., 2018-08-01.

Abstract

This study reports the synthesis, physicochemical characterization by X-ray powder diffraction (XRD), scanning electron microscopy (SEM) and solid-state MAS NMR (H-1, Na-23, Si-29 and Sn-119 MAS NMR) of a metallo-stannosilicate and its application as a heterogeneous catalyst for biodiesel production via ethanolysis and methanolysis routes using edible, non-edible an waste oils as feedstocks. XRD characterization of the metallo-stannosilicate has revealed a typical structure of mixed octahedral-pentahedral-tetrahedral material with an orthorhombic unit cell (a = 14.522 angstrom, b = 12.469 angstrom, and c = 10.654 angstrom). Sn-119 single-pulse MAS NMR results presented two resonance lines, at delta(1)= -683.8 ppm and delta(2) = -690.9 ppm, which were assigned to the fin octahedrally coordinated in the metallo-stannosilicate structure. Heterogenous catalytic studies in the transesterification of refined edible, non-edible, and waste oils have resulted in high yields of FAMEs and FAEEs (fatty acid methyl and ethyl esters), nevertheless the highest FAMES (98.2%) and FAEEs (96.6%) yields were obtained for non-edible microalgae oil extracted from the genetically modified heterotrophic algal strain Prototheca moriformis. Catalytic studies also using non-edible macaw palm oil (Acrocomia aculeata) with a high content of free fatty acids (FFAs) demonstrated that the catalyst could simultaneously perform esterification and transesterification reactions. These findings indicate the potential application of this novel metallo-stannosilicate in the production of renewable and environmentally clean biofuels, like biodiesel, using different sources of lipids feedstocks, notably those that do not compete with food production. (AU)

• FAPESP's process: 11/51851-5 - Syntheses and characterization of nanozeolites-enzymes complexes and their use as heterogeneous catalysts in the production of biodiesel by trans esterification of Palm Oil and algae oils (Dunaliella Salina and Haematococcus pluvialis) with ethanol
• Grantee: Jose Geraldo Nery
• Support Opportunities: Regular Research Grants