Improving electrochemical stability and electromechanical efficiency of ipmcs: tuning ionic liquid concentration

Author(s)

Tozzi, K. A. ; Goncalves, R. ; Barbosa, R. ; Saccardo, M. C. ; Zuquello, A. ; Sgreccia, E. ; Narducci, R. ; Scuracchio, C. H. ; di Vona, M. L.

• Document type: Journal article
• Source: Journal of Applied Electrochemistry; v. 53, n. 2, p. 15-pg., 2022-10-12.

Abstract

In the field of soft actuators, Ionomeric Polymer Metal Composites (IPMC)-like devices are a trend, exhibiting large displacement with low applied voltage. Its working mechanism is related to solvated electrolytes migration, thus the number of counterions exchanged with the polymeric membrane plays a key role in the device's performance. Although many kinds of inorganic and organic ions were used, there were few efforts to address a specific concentration value of electrolyte solutions. Ionic liquids (ILs) are used in IPMC to provide electrochemical stability; however, their mechanical performance is usually poor. In this study we aimed to determine a specific value of 1-butyl-3-methylimidazolium chloride ([BMIM]Cl) ionic liquid concentration between 0.1, 0.3, and 0.5 mol L-1 that grants electrochemical stability at different relative humidities with best electromechanical efficiency. We synthesized [BMIM]Cl and characterized it through Nuclear Magnetic Resonance (NMR), Fourier Transform Infrared Spectroscopy (FTIR), and Cyclic Voltammetry (CV). The electrochemical behavior of Nafion (R)/Pt-based IPMC exchanged with IL was studied through Electrochemical Impedance Spectroscopy (EIS), CV, and Chronoamperometry (CA). Electromechanical properties were measured through blocking force and displacement. All the IPMC tests were carried out at three distinct controlled humidities (30%, 60%, and 90%). Herein, we tuned the IL concentration in 0.3 mol L-1, delivering electrochemical stability with the best electromechanical yield regardless of the relative humidity. This result will be important when bringing electrolyte mixtures to further enhance the performance and efficiency of these devices. [GRAPHICS] . (AU)

• FAPESP's process: 18/09761-8 - Study and development of ionic polymer/metal composites for application in actuators and sensors aiming low cost and high performance
• Grantee: Roger Gonçalves
• Support Opportunities: Scholarships in Brazil - Post-Doctoral
• FAPESP's process: 18/07001-6 - Study and characterization of ionic conductive polymers used as artificial muscles: proposals for performance improvement
• Grantee: Carlos Henrique Scuracchio
• Support Opportunities: Regular Research Grants
• FAPESP's process: 20/02696-6 - Synthesis and characterization of artificial muscles based on SBS block copolymers with selective sulfonation of the phases
• Grantee: Matheus Colovati Saccardo
• Support Opportunities: Scholarships in Brazil - Doctorate
• FAPESP's process: 18/10843-9 - Study of deformation behavior of artificial muscles based on electroactive polymers: performance enhancement proposal
• Grantee: Matheus Colovati Saccardo
• Support Opportunities: Scholarships in Brazil - Master